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ScienceCh 3 Metals and Non-metals

Metals and Non-metals: Class 10 Science · Chapter 3

Science · Companion notes, simulations and practice · Official NCERT chapter PDF ↗

Published · Updated

  • 105 min
  • 35 practice questions
  • 24 MCQs

What you will learn in Metals and Non-metals

  • Compare metals and non-metals by lustre, hardness, malleability, ductility, conduction and sonority, and name the important exceptions
  • Classify oxides as basic, acidic or amphoteric and write balanced equations for metals reacting with oxygen, water and dilute acids
  • Build the reactivity series from experimental evidence and use it to predict displacement reactions
  • Show the formation of ionic compounds by electron transfer with electron-dot structures and explain their properties
  • Describe how metals are concentrated, extracted and refined according to their place in the reactivity series
  • Explain the conditions for rusting and how corrosion is prevented by coatings, galvanising and alloying

Original companion text aligned to NCERT Science Class 10, Chapter 3, pp. 37–57. Not affiliated with or endorsed by NCERT.

Look around a kitchen. The pressure cooker is aluminium or steel, the tap is often brass, and the gas stove has copper and steel parts. Now think of the coal in an angithi, the sulphur in a box of matches and the oxygen we breathe. They behave nothing like those utensils. In Class 9 you met elements as the simplest pure substances. Chemists sort most of them into two large families: metals (धातु) and non-metals (अधातु).

This chapter asks what makes a metal a metal. We test physical properties first, then see how metals react with oxygen, water, acids and each other's salts. Those results line up into the reactivity series. The series then explains why metals form ions, how they are won from rocks and purified, and why iron rusts while gold keeps its shine for centuries.

3.1 Physical Properties

The quickest way to tell materials apart is to look at them, tap them, bend them, and check whether heat or electricity passes through them. None of these tests changes what the substance is made of, so they reveal its physical properties.

3.1.1 Metals

Pick up a new steel spoon, a copper wire and a sheet of aluminium foil. All three shine, feel cool to the touch, and bend instead of snapping. Let us test such features one at a time, using samples of iron, copper, aluminium, magnesium, zinc and lead (Fig. 3.1).

5/5Lustre, malleability, ductility and sonority are typical of metals.

Fig. 3.1Four quick tests for a metal.

A two-by-two grid of small scenes. Step 1 highlights the top-left scene: sandpaper rubs a dull metal strip and leaves a bright, shiny patch, labelled lustre. Step 2 highlights the top-right scene: a hammer has flattened a lump of metal on an iron block into a wide thin sheet, labelled malleable. Step 3 highlights the bottom-left scene: a thick rod is pulled through a hole in a steel plate and comes out as a long thin wire, labelled ductile. Step 4 highlights the bottom-right scene: a metal bell is struck and sound waves spread out, labelled sonorous. Step 5 shows all four scenes together.

Sweet shops decorate kaju katli with varq, silver beaten so thin that it tears like tissue paper. The property of being hammered or rolled into thin sheets without cracking is called malleability (आघातवर्ध्यता). Gold and silver top the list of malleable metals.

Definition
Malleable

Able to be beaten or rolled into thin sheets without breaking.

ExampleAluminium foil for packing rotis; silver varq on sweets.

A metal that can be stretched into fine wire is ductile, and this property is its ductility (तन्यता). No metal is more ductile than gold: a single gram of it can be drawn into a wire more than a kilometre long. Malleability and ductility together let us shape metals into sheets, rods, vessels and wires to suit each use.

Definition
Ductile

Able to be drawn out into thin wires.

ExampleCopper for electric wiring; steel for guitar strings.

Most cooking vessels are made of aluminium, steel or copper, while their handles are often wood or plastic. Why use a metal for the pan but not for the handle? Activity 3.5 checks how well a metal carries heat.

Strip the end of an electric wire and you find bright copper or aluminium strands inside a jacket of PVC plastic. The strands carry the current; the jacket is there so that the current cannot pass into a person who touches the wire. Activity 3.6 builds a simple tester to check whether a solid conducts electricity.

1/3Copper closes the gap: the bulb glows.

Fig. 3.2A simple conduction tester.NCERT Fig. 3.2 · p. 39

Two cells, a bulb and wires form a loop with a gap at the bottom, where a sample is held between two crocodile clips. In step 1 the sample is a copper key and the bulb glows, with arrows showing current flowing round the loop. In step 2 the sample is a yellow lump of sulphur and the bulb stays dark, labelled no current. In step 3 the sample is a pencil lead made of graphite and the bulb glows again, showing that this non-metal conducts.

Drop a steel spoon and a wooden spoon on the floor. The steel one rings; the wooden one thuds. Metals that produce a ringing sound when struck are sonorous. That is why school bells, temple bells, ghungroo and cymbals are made of metal.

3.1.2 Non-metals

Only a small share of the elements are non-metals, but they matter enormously: the oxygen and nitrogen of air, the carbon in every living thing, the chlorine in bleach, the iodine in iodised salt, the sulphur on a matchstick head. At room temperature most of them are gases or brittle solids; red-brown bromine is the lone liquid. Do they pass the tests that metals pass? Try them.

Your table shows clear trends, but Table 3.2 shows that every trend has exceptions. So physical properties alone cannot sort all the elements.

Table 3.2Rules and their exceptions
Usual ruleException
Metals are solids at room temperatureMercury is a liquid
Metals melt only at high temperaturesGallium and caesium melt on a warm palm
Metals are hardLithium, sodium and potassium cut like butter; they are also light and melt easily
Non-metals are dullIodine crystals have a metallic lustre
Non-metals are soft or brittleDiamond, a form of carbon, is harder than any other natural material, and melts and boils only at very high temperatures
Non-metals do not conductGraphite, another form of carbon, conducts electricity

Diamond and graphite are both pure carbon. Different forms of the same element, with their atoms arranged differently, are called allotropes. The arrangement changes the properties completely: one is the hardest substance in nature, the other is soft enough to write with.

Compare

Metals and non-metals: physical properties

Metals

  • Lustrous
  • Usually hard; malleable and ductile
  • Good conductors of heat and electricity
  • Sonorous
  • Solids, except mercury

Non-metals

  • Mostly dull (iodine shines)
  • Brittle as solids; neither malleable nor ductile
  • Poor conductors (graphite conducts electricity)
  • Not sonorous
  • Solids or gases; bromine is a liquid

Because the physical rules leak, chemists rely more on chemical behaviour to classify an element. A good first test is to burn the element and find out what kind of oxide it makes.

4/4The gas in water turns blue litmus red: an acidic oxide.

Fig. 3.3A metal oxide and a non-metal oxide behave in opposite ways.NCERT Activity 3.8 · p. 40

Two columns. Step 1 shows magnesium ribbon held in tongs burning with a bright star of light and leaving white ash. Step 2 adds, below it, the ash mixed with water in a dish, with a strip of red litmus that has turned blue, labelled basic. Step 3 shows, in the right column, sulphur burning in a spoon with an upside-down test tube collecting the gas. Step 4 adds, below it, the test tube with water and a strip of blue litmus that has turned red, labelled acidic.

Magnesium burns
2 Mg+OX2→2 MgO
(3.1)
A basic solution
MgO+HX2O→Mg(OH)X2
(3.2)
Sulphur burns
S+OX2→SOX2
(3.3)
An acidic solution
SOX2+HX2O→HX2SOX3
(3.4)
where
HX2SOX3
sulphurous acid
Quick check
1 of 4
Which observation shows that graphite is not a typical non-metal?
Show answer

Answer (D) It conducts electricity

Most non-metals are poor conductors; graphite is an exception. Being black, solid or combustible fits many non-metals.
Practice · 2 questions

Practice: physical properties (NCERT in-text questions, p. 40): questions with answers

  1. Short answerEasyNCERT in-text Questions p. 40, Q1

    Name a metal that fits each description.

    1. It would pour out of a bottle on a cool morning.

      Show solution

      AnswerMercury

      Mercury is the only metal that is liquid at room temperature.

    2. A teacher can slice it with a table knife.

      Show solution

      AnswerSodium (or potassium, lithium)

      The alkali metals lithium, sodium and potassium are soft enough to cut with a knife.

    3. It would make the quickest-heating pan if cost did not matter.

      Show solution

      AnswerSilver

      Silver conducts heat best of all metals, with copper close behind.

    4. It conducts heat poorly compared with most metals.

      Show solution

      AnswerLead (or mercury)

      Among metals, lead and mercury carry heat relatively badly.

  2. Short answerEasyNCERT in-text Questions p. 40, Q2

    A goldsmith hammers one gold bead into a leaf so thin that light shows through it, and draws another bead into a fine wire for an earring. Name the property of gold used in each case and say what it means.

    Show solution

    AnswerMalleability for the leaf; ductility for the wire.

    The leaf uses malleability: a malleable metal can be hammered or rolled into thin sheets without cracking.

    The wire uses ductility: a ductile metal can be stretched or drawn into thin wires. Gold is the most malleable and the most ductile of all metals.

3.2 Chemical Properties of Metals

In this section you watch metals react with oxygen, water, dilute acids and solutions of other metals' salts. Keep a set of samples ready: aluminium, copper, iron, lead, magnesium and zinc, plus sodium for the teacher's demonstrations. Watch how fast each one reacts, because the speed tells you how reactive the metal is.

3.2.1 What happens when Metals are burnt in Air?

Heat most metals in air and they take up oxygen, turning into a metal oxide:

metal+oxygen⟶metal oxide
(3.5)

A bright copper wire held in a flame comes out black, because a skin of copper(II) oxide has formed on it. Aluminium powder burns to give white aluminium oxide:

2 Cu+OX2→2 CuO
(3.6)
4 Al+3 OX2→2 AlX2OX3
(3.7)

Chapter 2 treated metal oxides as bases, and most of them are: black copper(II) oxide, for instance, dissolves in dilute hydrochloric acid to give a blue-green salt solution. Aluminium oxide and zinc oxide are two-faced. In an acid they neutralise it like a base; in sodium hydroxide solution they neutralise that like an acid. Either way, a salt and water form. Oxides with this double behaviour are called amphoteric oxides (उभयधर्मी ऑक्साइड).

Definition
Amphoteric oxide

A metal oxide that reacts with both acids and bases to form a salt and water.

ExampleAluminium oxide, AlX2OX3, and zinc oxide, ZnO.

Acting as a base
AlX2OX3+6 HCl→2 AlClX3+3 HX2O
(3.8)
Acting as an acid
AlX2OX3+2 NaOH→2 NaAlOX2+HX2O
(3.9)
where
NaAlOX2
sodium aluminate, a salt
Example 3.1

Zinc oxide on both sides

Zinc oxide is the white powder in calamine lotion. Show that it is amphoteric by writing balanced equations for its reactions with dilute hydrochloric acid and with sodium hydroxide solution. The salt formed with the base is sodium zincate, NaX2ZnOX2.

Try it yourself first. Then reveal the solution one step at a time.

Drop most metal oxides into water and they just sit there. Sodium oxide and potassium oxide behave differently: they dissolve and react, leaving a strongly alkaline solution (an alkali is a base that dissolves in water):

NaX2O+HX2O→2 NaOH
(3.10)

Potassium oxide reacts in the same way to give potassium hydroxide, KOH. Activity 3.9 also showed that metals react with oxygen at very different speeds, as summed up in Table 3.4.

Table 3.4How some metals behave with oxygen
MetalWith oxygenSo we…
Potassium, sodiumReact so fast in open air that they can catch firestore them under kerosene, away from air and moisture
Magnesium, aluminium, zinc, leadGet a thin oxide skin at room temperaturerely on the skin: it shields the metal from further attack
IronA lump does not burn, but fine filings burn with sparks in a flameenjoy the sparks of a phuljhadi (sparkler), made with iron filings
CopperDoes not burn; hot copper gets a black coat of CuOclean the coat off with dilute acid
Silver, goldDo not react, even when strongly heateduse them for jewellery and coins

So far, sodium is clearly the most reactive of our samples, and magnesium comes next. Burning cannot rank zinc, iron, copper and lead against one another, however. We need other tests.

3.2.2 What happens when Metals react with Water?

4/4Pb, Cu, Ag and Au show no reaction with water.

Fig. 3.4Metals sorted by the conditions they need to react with water.NCERT Fig. 3.3 · p. 43

A ladder of four rows, revealed one per step. Step 1, cold water: potassium, sodium and calcium, with a note that the reaction can be violent. Step 2, hot water: magnesium, which reacts slowly and floats. Step 3, steam: aluminium, zinc and iron, which give the oxide and hydrogen. Step 4, no reaction: lead, copper, silver and gold. An arrow down the side reads less reactive.

Water is a gentler attacker than oxygen, so it sorts the metals more finely. Whenever a metal does react with water, one product is hydrogen gas; the other is the metal oxide or, if that oxide dissolves, the metal hydroxide. Go down the ladder of Fig. 3.4 one rung at a time.

Cold water, violently: potassium and sodium. A small piece skates over the surface, hissing, and gives out so much heat that the hydrogen often bursts into flame:

Very violent; heat is released
2 K+2 HX2O→2 KOH+HX2
(3.11)
Violent; heat is released
2 Na+2 HX2O→2 NaOH+HX2
(3.12)

Cold water, gently: calcium. It fizzes steadily, but too little heat is given out to light the hydrogen. Soon the lump rises and floats, carried by the hydrogen bubbles clinging to it:

Ca+2 HX2O→Ca(OH)X2+HX2
(3.13)

Hot water: magnesium. Cold water barely touches it. In hot water it slowly gives magnesium hydroxide and hydrogen, and it too ends up riding on its own bubbles:

With hot water
Mg+2 HX2O→Mg(OH)X2+HX2
(3.14)

Steam only: aluminium, zinc and iron. Cold and hot water leave them alone, but the red-hot metal in steam gives the oxide and hydrogen:

2 Al+3 HX2O(g)→AlX2OX3+3 HX2
(3.15)
Zn+HX2O(g)→ZnO+HX2
(3.16)
Example 3.2

Balancing iron with steam

Red-hot iron reacts with steam to give hydrogen and the black, magnetic oxide FeX3OX4. Write the balanced equation.

Try it yourself first. Then reveal the solution one step at a time.

Water leaves lead, copper, silver and gold untouched, whether it is cold, hot or steam. That is one reason copper is a good choice for water pipes and tanks, and why silver and gold ornaments stay bright in rain.

Quick check
1 of 4
Arrange these metals from most to least reactive with water.
  1. Calcium
  2. Potassium
  3. Copper
  4. Iron
  5. Magnesium
Show answer
Answer
  1. Potassium
  2. Calcium
  3. Magnesium
  4. Iron
  5. Copper
K reacts violently with cold water, Ca gently with cold water, Mg needs hot water, Fe needs steam and Cu does not react.

3.2.3 What happens when Metals react with Acids?

Chapter 2 showed that dilute acids attack many metals, producing hydrogen gas and a salt:

metal+dilute acid⟶salt+hydrogen
(3.17)

Do all metals react with acids, and equally fast? Activity 3.11 finds out.

3/3The bubbling ranks the metals: Mg > Al > Zn > Fe, and Cu does not react.

Fig. 3.5Bubbles of hydrogen show which metal reacts fastest.

Five test tubes of dilute hydrochloric acid stand in a rack, labelled magnesium, aluminium, zinc, iron and copper. In step 1 each tube has just received its piece of metal and nothing has happened yet. In step 2 bubbles of hydrogen rise: many from magnesium, fewer from aluminium and zinc, a few from iron and none from copper, and the magnesium tube is labelled warmest. Step 3 adds an arrow below the rack reading most reactive on the left to least reactive on the right.

Rank the tubes by fizz and by warmth and you get the same order: Mg > Al > Zn > Fe. The copper tube stays still and cool: dilute hydrochloric acid leaves copper untouched. For magnesium:

Mg+2 HCl→MgClX2+HX2
(3.18)

Aluminium, zinc and iron give similar equations, forming aluminium chloride, zinc chloride and iron(II) chloride.

3.2.4 How do Metals react with Solutions of other Metal Salts?

Oxygen, water and acids could not rank every metal, because some metals do not react with them at all. A sharper test is to put one metal into a solution of another metal's salt and see whether they swap places.

3/3Each zinc atom gives two electrons to a copper ion: zinc is oxidised, copper ions are reduced.

Fig. 3.6A metal higher in the series pushes a lower one out of its salt solution.NCERT Fig. 3.4 · p. 45

Two beakers. The left beaker holds blue copper sulphate solution with a grey zinc strip; the right beaker holds colourless zinc sulphate solution with a copper strip. In step 1 nothing has happened yet. In step 2, thirty minutes later, the zinc strip is covered with a brown coat of copper and the blue solution has become pale, while the right beaker is unchanged and labelled no change. Step 3 adds the ionic equation: zinc atoms give two electrons to copper ions and become zinc ions.

Here is the general rule. A metal higher in reactivity can displace, that is take the place of, a lower one in a compound, whether the compound is dissolved in water or melted. Turned around, it becomes a test: whenever metal A pulls metal B out of a solution of B's salt, A is the more reactive of the two.

A+salt of B⟶salt of A+B
(3.19)
Zn+CuSOX4→ZnSOX4+Cu
(3.20)

This is a displacement reaction, the type you met in Chapter 1. The same thing happens when an iron nail is left in copper(II) sulphate solution: the nail turns brown and the blue solution slowly becomes pale green iron(II) sulphate. So iron is more reactive than copper as well.

Example 3.3

Ranking metals from displacement results

Four metals W, X, Y and Z were placed, one at a time, in three salt solutions. The table shows what happened.

Table 3.6Results
MetalZinc sulphateLead nitrateSilver nitrate
Wno changedisplaceddisplaced
Xno changeno changeno change
Ydisplaceddisplaceddisplaced
Zno changeno changedisplaced

(a) Arrange W, X, Y and Z in order of decreasing reactivity. (b) Which of them could be copper?

Try it yourself first. Then reveal the solution one step at a time.

3.2.5 The Reactivity Series

Put all these results together, along with the displacement experiments of Chapter 1, and the common metals line up in a single list, from the most reactive at the top to the least reactive at the bottom. This list is the reactivity series (सक्रियता श्रेणी), also called the activity series (Fig. 3.7).

1/3The common metals in order of decreasing reactivity.

Fig. 3.7The reactivity series, with what it predicts.NCERT Table 3.2 · p. 45

Thirteen tiles step down a staircase from top left to bottom right: K, Na, Ca, Mg, Al, Zn, Fe, Pb, then H in square brackets with a dashed outline, then Cu, Hg, Ag and Au. The top is labelled most reactive and the bottom least reactive. Step 2 draws a line through hydrogen: the metals above it are marked as giving hydrogen with dilute acids and those below as not. Step 3 colours the tiles in four bands by how each metal is extracted: electrolysis for K to Al, reduction with carbon for Zn to Pb, heating alone for Cu and Hg, and found free for Ag and Au.

Hydrogen is not a metal, but it is placed in the series in square brackets, between lead and copper. Metals above it push hydrogen out of dilute acids; metals below it cannot. That is why copper, mercury, silver and gold give no hydrogen with dilute hydrochloric acid.

InteractiveDisplacement explorer

An interactive reactivity series. The learner picks one of eleven metals, from potassium to gold, and one of seven solutions: magnesium sulphate, zinc sulphate, iron(II) sulphate, lead nitrate, copper(II) sulphate, silver nitrate and dilute hydrochloric acid. A ladder of the series highlights the chosen metal and the metal (or hydrogen) in the solution. A panel then says whether a displacement happens, gives the balanced equation, and describes what you would see, such as a brown copper coat and a fading blue colour. Special cases are explained: potassium, sodium and calcium react with the water instead, aluminium starts slowly because of its oxide skin, and lead soon stops because an insoluble coat forms. A score counts the learner's correct predictions when the predict-first switch is on.

Fig. 3.8Pick a metal and a solution to predict whether a reaction happens, then read the equation and what you would see. The ladder shows where both metals sit in the reactivity series.
Quick check
1 of 4
A strip of lead is put in silver nitrate solution and another strip in zinc sulphate solution. What happens?
Show answer

Answer (A) Lead displaces silver only

Lead is below zinc but above silver in the series, so it can displace only silver.
Practice · 5 questions

Practice: reactivity (NCERT in-text questions, p. 46): questions with answers

  1. Short answerEasyNCERT in-text Questions p. 46, Q1

    A chemicals shop keeps lumps of potassium in a bottle of paraffin oil. Why? What would happen if the bottle were left open in a humid room?

    Show solution

    AnswerThe oil keeps air and moisture away; without it potassium would oxidise and could catch fire.

    Potassium reacts very fast with oxygen and violently with water, releasing enough heat to set fire to the hydrogen formed. Paraffin oil does not react with it and keeps air and moisture away.

    In an open bottle in humid air the oil would not protect the exposed metal, which would tarnish quickly and could catch fire on contact with water.

  2. Short answerMediumNCERT in-text Questions p. 46, Q2

    Write balanced equations for these reactions.

    1. Zinc heated in steam

      Show solution

      Zn+HX2O(g) →ZnO+HX2

    2. Magnesium with hot water

      Show solution

      Mg+2 HX2O →Mg(OH)X2+HX2

    3. Sodium with cold water

      Show solution

      2 Na+2 HX2O →2 NaOH+HX2

  3. Short answerMediumNCERT in-text Questions p. 46, Q3

    Four metals P, Q, R and S were added, one at a time, to solutions of zinc sulphate, iron(II) sulphate, copper(II) sulphate and silver nitrate. P displaced iron, copper and silver; Q displaced only silver; R displaced all four metals; S displaced copper and silver.

    1. Which of the four metals sits highest in the reactivity series?

      Show solution

      AnswerR

      R displaces zinc, iron, copper and silver, so it is above all of them.

    2. What would you see if S were added to copper(II) sulphate solution?

      Show solution

      AnswerA brown copper coat on S, and the blue colour fading

      The table shows that S displaces copper, so copper would deposit on S as a reddish-brown coat and the blue copper ions would be used up.

    3. Arrange P, Q, R and S in decreasing order of reactivity.

      1. R
      2. S
      3. P
      4. Q
      Show answer
      Answer
      1. R
      2. P
      3. S
      4. Q
      R displaces all four; P all but zinc; S only copper and silver; Q only silver.
  4. Short answerEasyNCERT in-text Questions p. 46, Q4

    Which gas is given off when a reactive metal is dropped into dilute sulphuric acid, and how would you test for it? Write the balanced equation for zinc with dilute sulphuric acid.

    Show solution

    AnswerHydrogen; it burns with a pop.

    The gas is hydrogen. A burning splint held at the mouth of the tube makes it burn with a 'pop'.

    For zinc: Zn+HX2SOX4 →ZnSOX4+HX2

  5. Short answerMediumNCERT in-text Questions p. 46, Q5

    What would you see if a strip of magnesium were placed in pale green iron(II) sulphate solution? Write the equation.

    Show solution

    AnswerA dark iron deposit on the magnesium; the green colour fades.

    Magnesium is above iron, so it displaces iron. A dark grey or black layer of iron forms on the strip and the pale green colour fades as colourless magnesium sulphate forms.

    The equation: Mg+FeSOX4 →MgSOX4+Fe

3.3 How do Metals and Non-metals React?

Why do metals react at all, and why do some react far more eagerly than others? Recall from Class 9 that the noble gases (helium, neon, argon …) hardly react. Their outermost shell is full: two electrons for helium and eight for the others. Other elements react in ways that give them such a full outer shell. Table 3.7 lists the shells of a few metals and non-metals.

Table 3.7Electrons in the shells of some elements
Electrons in shell
ElementAtomic numberKLMN
Neon (noble gas)1028––
Argon (noble gas)18288–
Sodium (metal)11281–
Magnesium (metal)12282–
Potassium (metal)192881
Calcium (metal)202882
Oxygen (non-metal)826––
Fluorine (non-metal)927––
Sulphur (non-metal)16286–
Chlorine (non-metal)17287–

Sodium is 2, 8, 1: a single electron sits alone in its third shell. Let that electron go, and the shell beneath, already holding a complete eight, becomes the outside of the particle. Now count charges: 11 protons in the nucleus but only 10 electrons. One positive charge is left over, so the particle is a positive ion, the sodium cation:

Na2,8,1⟶NaX+2,8+eX−
(3.21)

Chlorine, 2, 8, 7, is in the opposite position: its outer shell lacks just one electron to hold eight. Once it gains that electron, its 17 protons face 18 electrons, leaving one spare negative charge. It is now the chloride anion:

Cl2,8,7+eX−⟶ClX−2,8,8
(3.22)

Put the two together and each solves the other's problem: the electron sodium can spare is the one chlorine is missing (Fig. 3.9). The ions that result carry opposite charges and pull on each other strongly, and this electrostatic pull holds sodium chloride together. A grain of salt is therefore not a heap of separate 'NaCl molecules'. It is a vast, orderly stack of NaX+ and ClX− ions, each gripped by its neighbours.

3/3Both now have a full outer shell: NaX+ and ClX− attract each other.

Fig. 3.9Sodium chloride forms by the transfer of one electron.NCERT Fig. 3.5 · p. 47

Electron-dot diagrams. Step 1: a sodium atom with one outer electron drawn as a cross, labelled 2, 8, 1, and a chlorine atom with seven outer electrons drawn as dots, labelled 2, 8, 7. Step 2: the cross moves from sodium along a curved arrow and fills the gap on the chlorine atom. Step 3: an arrow leads to the products: a sodium ion in square brackets with a plus charge, labelled 2, 8, and a chloride ion in brackets with eight outer electrons and a minus charge, labelled 2, 8, 8; the two ions attract each other.

In Fig. 3.9 only the outer-shell electrons are drawn, as dots or crosses round the symbol. Such a drawing is an electron-dot structure. Crosses mark the metal's electrons so that you can follow where they go.

Magnesium (2, 8, 2) has two electrons to give, but a chlorine atom can take only one. So one magnesium atom reacts with two chlorine atoms (Fig. 3.10). Magnesium chloride, MgClX2, is made of MgX2+ cations and twice as many ClX− anions.

Mg2,8,2⟶MgX2+2,8+2eX−
(3.23)

3/3One MgX2+ ion and two ClX− ions make magnesium chloride.

Fig. 3.10One magnesium atom gives one electron to each of two chlorine atoms.NCERT Fig. 3.6 · p. 48

Electron-dot diagrams. Step 1: a magnesium atom with two outer electrons drawn as crosses, labelled 2, 8, 2, between two chlorine atoms that each have seven dots and a gap facing the magnesium. Step 2: curved arrows carry one cross to each chlorine atom. Step 3: an arrow leads down to the products: a magnesium ion in brackets with charge 2+, between two chloride ions in brackets, each with eight outer electrons and a minus charge; every ion now has a full outer shell.

Whenever a metal hands electrons over to a non-metal, the product is an ionic compound (आयनिक यौगिक), also known as an electrovalent compound.

Definition
Ionic (electrovalent) compound

A compound of positive and negative ions held together by electrostatic attraction, formed when a metal transfers electrons to a non-metal.

ExampleSodium chloride, magnesium chloride and calcium oxide.

Example 3.4

Potassium sulphide by electron transfer

Show how potassium (atomic number 19) and sulphur (atomic number 16) form potassium sulphide. Name the ions and write the formula.

Try it yourself first. Then reveal the solution one step at a time.

Oxides are drawn the same way (Fig. 3.11). Oxygen (2, 6) needs two electrons. A lithium atom (2, 1) can give only one, so two lithium atoms are needed and the formula is LiX2O; a calcium atom gives both its outer electrons, so calcium oxide is simply CaO.

Fig. 3.11Two lithium atoms, or one calcium atom, supply the two electrons an oxygen atom needs.

Two rows of electron-dot diagrams. Top row: two lithium atoms, each with one outer electron drawn as a cross, send their electrons along curved arrows to an oxygen atom with six dots; the products are two lithium ions in brackets with a plus charge each and an oxide ion in brackets with eight outer electrons and a charge of 2 minus. Bottom row: one calcium atom with two crosses sends both electrons to an oxygen atom; the products are a calcium ion with charge 2 plus and an oxide ion with charge 2 minus.

Compare

Metals and non-metals: chemical behaviour

Metals

  • Form basic oxides (a few are amphoteric)
  • Lose electrons to form positive ions
  • Those above hydrogen give hydrogen with dilute acids
  • Often act as reducing agents (give electrons)

Non-metals

  • Form acidic or neutral oxides (CO is neutral)
  • Gain electrons to form negative ions
  • Do not give hydrogen with dilute acids
  • Combine with hydrogen to form hydrides such as HX2S and NHX3

3.3.1 Properties of Ionic Compounds

The ions explain every one of these observations:

  • Hard but brittle solids. Strong attractions between oppositely charged ions make the crystals hard. A sharp blow shifts one layer of ions against the next, like charges come face to face and repel, and the crystal shatters.
  • High melting and boiling points. To melt the crystal, the ions must be shaken loose from one another, and their strong attraction makes that very costly in energy (Table 3.8).
  • Soluble in water, not in kerosene or petrol. Water molecules can pull the ions apart; kerosene and petrol cannot.
  • Conduct electricity when molten or dissolved, but not as solids. A current needs charged particles that can move. In the solid the ions are locked in place; melting or dissolving sets them free to drift towards the oppositely charged electrodes (Fig. 3.12).
Table 3.8Ionic compounds melt and boil far higher than molecular substances
SubstanceTypeMelts (°C)Boils (°C)
Sodium chlorideionic8011465
Potassium chlorideionic7701420
Magnesium oxideionic28523600
Watermolecular0100
Ethanolmolecular−11478
Naphthalenemolecular80218

3/3Dissolved ions are free to move too, so the solution conducts.

Fig. 3.12Ions must be free to move to carry a current.NCERT Fig. 3.8 · p. 48

A cell, a bulb and two electrodes, marked plus and minus, dip into a sample of an ionic compound drawn as plus and minus ions. In step 1 the sample is solid: the ions sit in a neat grid, cannot move, and the bulb is dark. In step 2 the sample is molten over a flame: the ions are jumbled and drift, positive ions to the negative electrode and negative ions to the positive one, and the bulb glows. In step 3 the compound is dissolved in water: the ions are spread out and moving, and the bulb glows.

Quick check
1 of 4
Why does solid sodium chloride not conduct electricity?
Show answer

Answer (C) Its ions cannot move from place to place

The solid is made of ions, but they are held in fixed positions. Melting or dissolving lets them move and carry the current.
Practice · 2 questions

Practice: ionic compounds (NCERT in-text questions, p. 49): questions with answers

  1. DiagramMediumNCERT in-text Questions p. 49, Q1

    Potassium has atomic number 19, fluorine 9 and calcium 20.

    1. Draw the electron-dot structures of potassium, fluorine and calcium.

      Show solution

      K (2, 8, 8, 1) has one outer electron: K with one cross. F (2, 7) has seven: F with three pairs of dots and one single dot. Ca (2, 8, 8, 2) has two: Ca with two crosses.

    2. Show the formation of potassium fluoride and calcium fluoride by the transfer of electrons.

      Show solution

      Potassium fluoride: potassium's single cross moves to the gap beside fluorine. You get [K]⁺ and [F]⁻, the fluoride ion holding eight outer electrons (seven dots and one cross). Formula KF.

      Calcium fluoride: one fluorine atom can take only one electron, so calcium's two crosses go to two different fluorine atoms, just as in Fig. 3.10. You get [Ca]²⁺ and two [F]⁻ ions. Formula CaFX2.

    3. Name the ions present in each compound.

      Show solution

      AnswerKF: K⁺ and F⁻. CaF₂: Ca²⁺ and F⁻.

      Potassium fluoride contains KX+ and FX− in the ratio 1 : 1. Calcium fluoride contains CaX2+ and FX− in the ratio 1 : 2.

  2. Short answerMediumNCERT in-text Questions p. 49, Q2

    Furnaces are lined with bricks of magnesium oxide. Explain, in terms of its particles, why magnesium oxide survives such high temperatures.

    Show solution

    AnswerStrong attraction between Mg²⁺ and O²⁻ ions needs huge energy to overcome.

    Magnesium oxide is an ionic compound: a giant stack of MgX2+ and OX2− ions held by strong electrostatic attraction. Melting means breaking up this regular stack, which needs a very large amount of energy. With doubly charged ions the attraction is especially strong, so magnesium oxide melts only at about 2850 °C.

3.4 Occurrence of Metals

The bauxite dug from the hills of Odisha, the haematite of Chhattisgarh and the zinc ore of Rajasthan all come from the Earth's crust, the main store of the metals we use. The sea is a second, smaller store, holding salts such as sodium chloride and magnesium chloride in solution. Any element or compound formed by nature in the crust is a mineral (खनिज). When a mineral is so rich in a metal that extracting the metal pays, it is called an ore (अयस्क).

Definition
Ore

A mineral from which a metal can be extracted profitably.

ExampleBauxite is the ore of aluminium; haematite, FeX2OX3, is an ore of iron. Every ore is a mineral, but not every mineral is an ore.

3.4.1 Extraction of Metals

Where a metal sits in the reactivity series tells you how nature stores it (Table 3.9). Unreactive metals have lasted for millions of years without combining with anything; reactive ones joined up with other elements long ago. Oxides are especially common among ores, because oxygen is both reactive and plentiful.

Table 3.9How a metal's reactivity decides the way it is found
Part of the seriesHow the metals occurExamples
Bottom (least reactive)Often free (native), as the metal itself; copper and silver also as sulphide or oxide oresgold, silver, platinum, copper
MiddleCombined; their ores are usually oxides, sulphides or carbonateszinc, iron, lead
Top (most reactive)Never free; always combinedpotassium, sodium, calcium, magnesium, aluminium

Extraction follows the same three-way split: one approach for metals of low reactivity, one for the middle and one for the top (third step of Fig. 3.7). Getting a metal out of its ore and purifying it is called metallurgy (धातुकर्म). Fig. 3.13 shows the route an ore follows.

4/4Hg, Cu: heating the sulphide in air is enough. Every metal is then refined.

Fig. 3.13From ore to pure metal: the method depends on reactivity.NCERT Fig. 3.10 · p. 50

A flow chart. Step 1: an ore box leads to concentration, where gangue is removed. Step 2 highlights the left branch for the most reactive metals, such as sodium: electrolysis of the molten compound gives the metal. Step 3 highlights the middle branch for metals like zinc: a sulphide ore is roasted, or a carbonate ore calcined, to give the oxide, which is then reduced with carbon. Step 4 highlights the right branch for metals of low reactivity such as mercury: heating the sulphide in air is enough. All three branches end at the metal, which is then refined to give pure metal.

3.4.2 Enrichment of Ores

Before cooking, rice and dal are picked clean of small stones and husk. Ore needs the same treatment on a giant scale. Rock from a mine carries plenty of soil, sand and stone, called gangue (गैंग), which has to go before any metal is extracted. This clean-up is called concentration or enrichment of the ore. The trick is always to exploit some property, physical or chemical, in which the ore and the gangue differ.

For example, heavy ore particles can be washed free of lighter sand in a stream of water. A magnetic iron ore can be picked out of non-magnetic rock with a magnet. Sulphide ores are often separated by froth flotation: the ore particles cling to an oily froth and float off, while the gangue sinks.

3.4.3 Extracting Metals Low in the Activity Series

Near the bottom of the series, metals hold oxygen so feebly that heat alone can release them. Mercury comes from cinnabar, mercury(II) sulphide. Roast cinnabar in air and its sulphur leaves as sulphur dioxide, leaving mercury(II) oxide; keep heating and the oxide itself breaks up into mercury and oxygen:

2 HgS+3 OX2→heat2 HgO+2 SOX2
(3.24)
2 HgO→heat2 Hg+OX2
(3.25)

Copper glance, CuX2S, yields copper in a similar way. Part of the sulphide is heated in air to copper(I) oxide, which then reacts with the rest of the sulphide:

2 CuX2S+3 OX2→heat2 CuX2O+2 SOX2
(3.26)
2 CuX2O+CuX2S→heat6 Cu+SOX2
(3.27)

3.4.4 Extracting Metals in the Middle of the Activity Series

Zinc, iron, lead and copper sit in the middle of the series and are usually mined as sulphides or carbonates. Chemists would rather start from an oxide, which is far easier to reduce, so the first job is to convert the ore:

  • Roasting (भर्जन): heating a sulphide ore strongly in plenty of air.
  • Calcination (निस्तापन): heating a carbonate ore strongly in little or no air.
Roasting
2 ZnS+3 OX2→heat2 ZnO+2 SOX2
(3.28)
Calcination
ZnCOX3→heatZnO+COX2
(3.29)

Next the oxide is heated with a reducing agent, most often carbon in the form of coke, which carries the oxygen away. Recall from Chapter 1 that removing oxygen is reduction. Every extraction of a metal from its compound is, at heart, a reduction.

ZnO+C→Zn+CO
(3.30)
Example 3.5

Lead from two different ores

Lead is mined mostly as galena, lead(II) sulphide (PbS), and sometimes as cerussite, lead(II) carbonate (PbCOX3). For each ore, name the step that turns it into lead(II) oxide and write its equation. Then show how lead is obtained from the oxide.

Try it yourself first. Then reveal the solution one step at a time.

Carbon is not the only oxygen thief. A metal high in the series, such as sodium, calcium or aluminium, can strip the oxygen from the oxide of a metal lower down. Heating manganese dioxide with powdered aluminium, for instance, gives manganese:

3 MnOX2+4 Al→3 Mn+2 AlX2OX3+heat
(3.31)

Here aluminium gains oxygen, so it is oxidised, while manganese dioxide loses oxygen and is reduced.

Reactions of this kind give out heat so fast that the freed metal comes out as a liquid. The best known is the thermit reaction of iron(III) oxide with aluminium, which supplies white-hot molten iron for welding rails and mending broken machine parts on the spot:

Thermit reaction
FeX2OX3+2 Al→2 Fe+AlX2OX3+heat
(3.32)

Chromium metal is made in the same way, by heating chromium(III) oxide with aluminium powder:

CrX2OX3+2 Al→2 Cr+AlX2OX3+heat
(3.33)
Example 3.6

Who is oxidised, who is reduced?

Look at the reaction in (3.33). (a) Which substance is oxidised and which is reduced? (b) Why can aluminium do this job? (c) Why does the chromium come out as a liquid?

Try it yourself first. Then reveal the solution one step at a time.

3.4.5 Extracting Metals towards the Top of the Activity Series

Try heating sodium oxide, magnesium oxide or aluminium oxide with carbon and nothing happens: these metals grip oxygen more tightly than carbon can. They are won instead by electrolytic reduction, in which an electric current, passed through the molten compound, does the reducing.

For sodium, magnesium and calcium the starting material is the molten chloride. As the current flows through the melt, the metal builds up on the cathode (the negative electrode) and chlorine gas escapes at the anode (the positive electrode). With molten sodium chloride:

At the cathode
NaX++eX−→Na
(3.34)
At the anode
2 ClX−→ClX2+2 eX−
(3.35)

At the cathode, sodium ions gain electrons, so they are reduced. Aluminium is obtained in the same way, by electrolysing aluminium oxide. The compound must be molten rather than dissolved in water: in a water solution, hydrogen from the water would be released at the cathode instead of sodium.

3.4.6 Refining of Metals

Copper for electric wiring must be extremely pure, because even small amounts of impurity raise its resistance. Metal straight from a furnace is not that pure, so it is refined. The most widely used method is electrolytic refining (विद्युत-अपघटनी परिष्करण), applied to copper, nickel, zinc, tin, silver, gold and others.

Take copper (Fig. 3.14). A thick slab of the impure metal is connected as the anode, a thin sheet of pure copper as the cathode, and both dip into acidified copper(II) sulphate solution. As current flows, copper atoms leave the anode as CuX2+ ions, cross the solution, and settle on the cathode as fresh, pure metal:

At the anode
Cu→CuX2++2 eX−
(3.36)
At the cathode
CuX2++2 eX−→Cu
(3.37)

The impurities part company. Those that dissolve stay behind in the solution; those that do not, often including precious silver and gold, drop to the floor of the tank under the anode as anode mud.

Definition
Electrolytic refining

Purifying a metal by electrolysis, with the impure metal as the anode, a thin sheet of the pure metal as the cathode, and a solution of a salt of the metal as the electrolyte.

ExampleImpure copper is refined in acidified copper(II) sulphate solution.

3/3The anode shrinks, the cathode grows, and insoluble impurities collect as anode mud.

Fig. 3.14Electrolytic refining of copper.NCERT Fig. 3.12 · p. 52

A tank of blue acidified copper sulphate solution with a thin pure-copper cathode on the left, connected to the negative terminal of a power supply, and a thick impure-copper anode on the right, connected to the positive terminal. In step 1 nothing flows. In step 2 copper ions, labelled Cu 2 plus, move from the anode across the solution to the cathode. In step 3 the anode has become thinner, the cathode thicker, and a heap of anode mud lies on the floor of the tank under the anode.

Quick check
1 of 4
Match each starting material with the right treatment.

Tap an item on the left, then its match on the right.

Show answer
Answer
  • Gold nuggets : found free; just separate
  • Zinc blende, ZnS : roast, then reduce with carbon
  • Molten sodium chloride : electrolysis
  • Impure copper : electrolytic refining
Gold occurs native; a middle metal's sulphide is roasted then reduced with carbon; a top metal needs electrolysis of its melt; impure copper is purified as an anode.
Practice · 3 questions

Practice: occurrence and extraction (NCERT in-text questions, p. 53): questions with answers

  1. Short answerEasyNCERT in-text Questions p. 53, Q1

    A company finds two deposits containing aluminium compounds. One is bauxite rich in aluminium oxide. The other is a clay holding only a little aluminium that would cost more to extract than it is worth.

    1. Which deposit is an ore, and which is only a mineral? Explain.

      Show solution

      AnswerBauxite is an ore; the clay is a mineral but not an ore.

      Both are minerals, because nature formed them in the Earth's crust. Only bauxite is an ore, since aluminium can be extracted from it profitably.

    2. The bauxite is mixed with sand and red soil. What are these called, and why are they removed first?

      Show solution

      AnswerGangue; it would waste energy and contaminate the metal.

      The unwanted sand and soil are gangue. They are removed first (concentration) so that energy is not wasted on processing them and they do not end up as impurities in the metal.

  2. Short answerEasyNCERT in-text Questions p. 53, Q2

    Name two metals that a prospector might find as nuggets of the pure metal, and explain why they occur free.

    Show solution

    AnswerGold and platinum (also silver, copper).

    Gold and platinum (and sometimes silver and copper) occur free. They are so unreactive that they have not combined with oxygen, sulphur or other elements over geological time.

  3. Short answerEasyNCERT in-text Questions p. 53, Q3

    At a smelter, zinc oxide is heated with coke and zinc metal is obtained. What type of chemical change happens to the zinc oxide, and what job does the coke do?

    Show solution

    AnswerReduction; coke is the reducing agent.

    Zinc oxide loses its oxygen, so it is reduced: ZnO+C →Zn+CO. The coke (carbon) takes the oxygen and is itself oxidised to carbon monoxide; it acts as the reducing agent.

3.5 Corrosion

Leave a shiny metal in air long enough and its surface changes. You met three examples in Chapter 1 (Table 3.10). This slow eating away of a metal by the air, moisture or chemicals around it is called corrosion (संक्षारण).

Table 3.10Three familiar kinds of corrosion
MetalWhat you seeWhat has formedCaused by
SilverOrnaments and plates turn blacksilver sulphidesulphur compounds in the air
CopperThe brown surface turns green, as on old domes and statuesbasic copper carbonatemoist carbon dioxide in the air
IronA brown, flaky coatingrust, a hydrated iron(III) oxideoxygen and water together

Rusting is the costliest kind: bridges, ships, cars and railway coaches lose iron to it every year. Activity 3.14 finds out what iron needs in order to rust.

3/3Iron rusts only when both oxygen (air) and water are present.

Fig. 3.15Rusting needs both air and water.NCERT Fig. 3.13 · p. 53

Three closed glass jars, A, B and C, each with an iron nail. Jar A has a little tap water around the lower part of the nail. Jar B is filled with boiled water under a thin layer of oil. Jar C is dry, with small silica-gel sachets on the floor. In step 1, on day 0, all three nails are clean and grey. In step 2, on day 5, the nail in jar A is covered with brown rust, while the nails in B and C are still clean. Step 3 labels what each jar provides: air and water in A, water only in B, air only in C.

So anything that keeps air or water away from iron slows down rusting.

3.5.1 Prevention of Corrosion

There are two ways to beat rust. One is a barrier that keeps air and water off the iron: paint, oil, grease, or a plating of chromium (chrome plating) or zinc (galvanising). The other is to change the iron itself by making an alloy. Anodising, which you met earlier, guards aluminium in a similar barrier-like way. Paint, oil and grease help only while the layer is unbroken.

Galvanisation (यशदलेपन) gives iron or steel a thin coat of zinc; corrugated roofing sheets, buckets and fence wire are usually galvanised. Here is the surprise: even where the zinc gets scratched through, the iron underneath does not rust. Zinc is more reactive than iron, so where both metals meet air and water, the zinc is attacked first and the iron is spared (Fig. 3.16).

Definition
Galvanisation

Protecting iron or steel from rusting by giving it a thin coat of zinc.

ExampleGalvanised iron (GI) roofing sheets and buckets.

4/4Tin is less reactive than iron, so the exposed iron rusts.

Fig. 3.16Zinc protects iron even through a scratch; tin does not.

Two cut-away views side by side: on the left iron with a zinc coating, on the right iron with a tin coating. In step 1 both coatings are whole. In step 2 a scratch cuts through each coating down to the iron, and a drop of water sits in each scratch. In step 3, on the zinc side, the zinc next to the scratch corrodes away while the iron below stays clean, labelled zinc corrodes first. In step 4, on the tin side, brown rust grows in the scratch and spreads under the tin, labelled iron rusts.

Tin-plated steel behaves the other way round. Tin is less reactive than iron, so it protects only while it is unbroken; through a scratch, the iron underneath rusts. Tin is still chosen for food cans because it is unreactive and harmless, whereas zinc would react with acidic foods.

Almost every iron object you see is really an alloy. Pure iron is too soft for most jobs and stretches easily when hot. A pinch of carbon, usually less than one percent, turns it into steel, which is hard and strong. Add chromium and nickel and you get stainless steel, tough and rust-proof: think of a steel thali or tiffin box.

Steel is one example of an alloy (मिश्रातु): a metal blended so evenly with other metals, or with a non-metal, that the mixture is the same all through (homogeneous). Alloys are made by melting the main metal, dissolving the other elements in the melt in measured amounts, and letting it cool and set. An alloy containing mercury has a special name: an amalgam.

Definition
Alloy

A uniform (homogeneous) mixture in which a metal is blended with other metals, or with a non-metal such as carbon.

ExampleBrass (copper and zinc); steel (iron and carbon).

Alloying changes properties in useful ways (Table 3.11). An alloy usually melts at a lower temperature, and conducts electricity less well, than the pure metals in it. So house wiring is pure copper; brass and bronze go into taps, statues and bells; and solder, which melts easily, joins electrical wires.

Table 3.11Some common alloys
AlloyMade ofUseful becauseUsed for
Steeliron + a little carbonhard and strongbuildings, rails, tools
Stainless steeliron + chromium + nickelhard; does not rustutensils, surgical tools
Brasscopper + zincgolden; does not corrode easilytaps, lamps, musical instruments
Bronzecopper + tinhard; resists corrosion; rings wellstatues, bells, medals
Solderlead + tinlow melting pointjoining electrical wires
22-carat goldgold + copper or silverharder than pure goldjewellery
Quick check
1 of 4
A galvanised iron bucket gets a deep scratch. Why doesn't the exposed iron rust quickly?
Show answer

Answer (B) Zinc is more reactive, so it corrodes in place of the iron

Zinc sits above iron in the series, so it corrodes first and protects the iron. A less reactive coating, such as tin, would not.
Practice · 3 questions

Practice: corrosion and alloys (NCERT in-text questions, p. 55): questions with answers

  1. Quick answerMediumNCERT in-text Questions p. 55, Q1

    Powders of aluminium, iron and lead are each heated with calcium oxide, iron(III) oxide and lead(II) oxide. Pick every pair in which the metal takes the oxygen and frees the other metal.

    Select all that apply
    Show solution

    Use the series Ca > Al > Fe > Pb. A metal reacts only with the oxide of a metal below it: Al with FeX2OX3 and with PbO, and Fe with PbO. No metal here is above calcium, so CaO is never reduced.

  2. Short answerEasyNCERT in-text Questions p. 55, Q2

    Name two metals that stay bright for centuries without corroding, and say why.

    Show solution

    AnswerGold and platinum.

    Gold and platinum are so unreactive that air, water and the sulphur compounds in air do not attack them. (Silver is also unreactive but slowly blackens with sulphur compounds.)

  3. Short answerEasyNCERT in-text Questions p. 55, Q3

    Define an alloy in your own words. Which alloy would an electrician use to join wires, and what is it made of?

    Show solution

    AnswerA uniform blend of a metal with other elements; solder is lead + tin.

    An alloy is a metal blended uniformly with other metals, or with a non-metal such as carbon, so that every part of it has the same make-up. Solder, made of lead and tin, melts easily and is used to join electrical wires.

Recap

Metals and Non-metals: key points and summary

  1. Metals are lustrous, malleable, ductile, sonorous and good conductors of heat and electricity; all are solid at room temperature except mercury (Section 3.1.1).
  2. Non-metals are usually dull, brittle and poor conductors, with exceptions: graphite conducts, iodine is lustrous, diamond is very hard and bromine is a liquid (Section 3.1.2).
  3. Metals form basic oxides; non-metals form acidic or neutral oxides. AlX2OX3 and ZnO react with both acids and bases: they are amphoteric (Section 3.2.1).
  4. Metals differ in how readily they react with oxygen, water and dilute acids (Section 3.2.2, Section 3.2.3).
  5. The reactivity series runs from potassium at the top, through sodium, calcium, magnesium, aluminium, zinc, iron, lead, [hydrogen], copper, mercury and silver, to gold at the bottom (Section 3.2.5).
  6. Metals above hydrogen push it out of dilute acids, and a metal higher in the series takes the place of a lower one in its salt solution (Section 3.2.4).
  7. Metals lose electrons to form positive ions and non-metals gain them to form negative ions; the ions make up ionic compounds (Section 3.3).
  8. Non-metals cannot push hydrogen out of dilute acids, and they combine with hydrogen to form hydrides (Section 3.3).
  9. Ionic compounds are hard, brittle solids with high melting points; they dissolve in water but not in kerosene, and conduct when molten or dissolved (Section 3.3.1).
  10. Metals occur free or as compounds in minerals; an ore is a mineral from which a metal can be extracted profitably (Section 3.4).
  11. Metallurgy: concentrate the ore, convert it to the oxide by roasting or calcination, reduce it by heating, with carbon or by electrolysis according to reactivity, then refine (Section 3.4.1).
  12. Electrolytic refining uses the impure metal as anode and pure metal as cathode in a solution of the metal's salt (Section 3.4.6).
  13. Corrosion is the slow attack of a metal by its surroundings; iron rusts only when air and water are both present (Section 3.5).
  14. Barriers (paint, oil, grease, chromium or zinc coats) and alloying stop rusting; an alloy is a metal blended evenly with other metals or a non-metal (Section 3.5.1).
Practice · 20 questions

Practice questions with answers (NCERT “Exercises”)

  1. Quick answerEasyNCERT Exercises Q1

    Which of these pairs will give a displacement reaction? Pick all that apply.

    Select all that apply
    Show answer
    Answer
    • (A) Zinc in copper(II) sulphate solution
    • (D) Lead in silver nitrate solution
    Zinc is above copper and lead is above silver, so those two react. Silver is below zinc and iron is below magnesium, so those two do not.
  2. Quick answerEasyNCERT Exercises Q2

    Pick every method that would keep an iron tawa from rusting while it is stored through the monsoon.

    Select all that apply
    Show answer
    Answer
    • (A) Wiping it dry and rubbing on a thin film of oil
    • (D) Storing it in a box with a silica-gel sachet
    Oil keeps out air and water, and silica gel keeps the air dry. Leaving it wet or wrapping it in salty paper speeds up rusting.
  3. Quick answerMediumNCERT Exercises Q3

    An element X burns in air to give a white solid that melts only above 2500 °C. The solid dissolves in water, and the solution turns red litmus blue. X is most likely

    Show answer

    Answer (C) calcium

    Calcium oxide is ionic (very high melting point) and reacts with water to give the alkali calcium hydroxide. Sulphur and phosphorus give acidic oxides; copper(II) oxide is black and insoluble.
  4. Quick answerMediumNCERT Exercises Q4

    Brass and copper cooking vessels used to be coated with tin (kalai) before sour dishes were cooked in them. Why tin rather than zinc?

    Show answer

    Answer (B) Zinc is more reactive, so sour food would attack it

    Zinc is above tin in the series, so the acids in sour food would react with a zinc coating and dissolve zinc salts into the food. Tin is much less reactive and harmless.
  5. Short answerMediumNCERT Exercises Q5

    Your lab has only a hammer and an LED tester (a cell, an LED and wires).

    1. Describe two tests you would use to sort unknown solid elements into metals and non-metals.

      Show solution

      AnswerHammer test and conduction test.

      Hammer test: strike the sample on a hard surface. A metal flattens (malleable) and may ring (sonorous); a non-metal such as sulphur or charcoal crumbles.

      Conduction test: clip the sample into the tester. If the LED lights, the sample conducts, as metals do; most non-metals do not.

    2. How reliable are these tests? Name an element that would mislead each one.

      Show solution

      AnswerGraphite misleads the conduction test; soft alkali metals can mislead the hammer test.

      Both tests work for most samples but not all. Graphite is a non-metal that lights the LED. A metal such as zinc may crack when cold and needs several blows, and sodium is too soft and too reactive to test this way. Chemical tests, such as the nature of the oxide, settle doubtful cases.

  6. Short answerMediumNCERT Exercises Q6

    A white oxide dissolves in dilute hydrochloric acid and also in sodium hydroxide solution. What kind of oxide is it? Suggest two oxides it could be, and write one equation for each reaction of one of them.

    Show solution

    AnswerAmphoteric, e.g. ZnO or Al₂O₃.

    An oxide that reacts with both acids and bases to give a salt and water is amphoteric. Zinc oxide and aluminium oxide are both white amphoteric oxides. For zinc oxide:

    With the acid: ZnO+2 HCl →ZnClX2+HX2O

    With the alkali: ZnO+2 NaOH →NaX2ZnOX2+HX2O

  7. Short answerEasyNCERT Exercises Q7

    You have strips of copper, magnesium, silver and zinc, and some dilute sulphuric acid. Which strips will give hydrogen? Explain using the reactivity series.

    Show solution

    AnswerMagnesium and zinc will; copper and silver will not.

    Magnesium and zinc are above hydrogen in the reactivity series, so they displace it from the acid: bubbles of hydrogen appear. Copper and silver are below hydrogen, so they cannot displace it and nothing happens.

  8. Short answerMediumNCERT Exercises Q8

    A refinery purifies silver by electrolysis.

    1. What is used as the anode?

      Show solution

      AnswerA block of impure silver

      The impure silver is made the anode, so that it dissolves.

    2. What is used as the cathode?

      Show solution

      AnswerA thin strip of pure silver

      Pure silver deposits on a thin strip of pure silver, the cathode.

    3. What is the electrolyte?

      Show solution

      AnswerA solution of a silver salt, such as silver nitrate

      The electrolyte must carry silver ions, so a solution of a soluble silver salt such as silver nitrate is used.

    4. Where will any gold in the impure silver end up?

      Show solution

      AnswerIn the anode mud

      Gold is less reactive than silver and does not dissolve, so it falls below the anode as anode mud.

  9. Short answerMediumNCERT Exercises Q9

    Ananya burns a little sulphur in a deflagrating spoon inside a gas jar, then lowers strips of litmus into the jar.

    1. What happens to a strip of dry blue litmus paper?

      Show solution

      AnswerNo change

      Dry sulphur dioxide is not an acid by itself, so dry litmus does not change.

    2. What happens to a strip of moist blue litmus paper?

      Show solution

      AnswerIt turns red

      On the moist paper the gas dissolves to form sulphurous acid, which turns blue litmus red.

    3. Write balanced equations for the burning and for the gas dissolving in water.

      Show solution

      Burning: S+OX2→SOX2.

      Dissolving: SOX2+HX2O →HX2SOX3.

  10. Short answerEasyNCERT Exercises Q10

    Suggest a suitable way to prevent rusting for each object.

    1. A bicycle chain

      Show solution

      AnswerOiling or greasing

      Oil or grease keeps out air and water and also lets the links move freely; paint would crack off.

    2. A corrugated iron roof

      Show solution

      AnswerGalvanising

      A zinc coating protects even where it gets scratched.

    3. The body of a car

      Show solution

      AnswerPainting (over a primer)

      Paint forms a barrier and gives a good finish; many car bodies are also galvanised underneath.

  11. Quick answerEasyNCERT Exercises Q11

    Carbon dioxide dissolves in water to give a solution with a pH below 7. This shows that oxides of non-metals are generally

    Show answer

    Answer (B) acidic (a few are neutral)

    Non-metal oxides such as COX2 and SOX2 are acidic. A few, such as carbon monoxide, are neutral.
  12. Short answerMediumNCERT Exercises Q12

    Give reasons.

    1. Silver and gold coins from ancient times are still found in good condition.

      Show solution

      Silver and gold are near the bottom of the reactivity series, so air and water barely attack them. They keep their shape and lustre for centuries.

    2. A teacher keeps potassium under paraffin oil, never in water.

      Show solution

      Potassium reacts violently with water and quickly with air, and the hydrogen formed can catch fire. Paraffin oil does not react with it and keeps both air and moisture away.

    3. Aluminium is high in the reactivity series, yet pressure-cooker bodies are made of it.

      Show solution

      A thin, tough layer of aluminium oxide forms on the surface and stops further reaction. Aluminium is also light and a good conductor of heat.

    4. Galena (PbS) is converted into lead(II) oxide before lead is extracted.

      Show solution

      It is much easier to reduce a metal oxide (with carbon) than a sulphide, so the sulphide ore is first roasted to the oxide.

  13. Short answerMediumNCERT Exercises Q13

    Brass diyas turn dull and greenish some weeks after Diwali. Why does rubbing them with a paste of lemon juice (or tamarind) and salt make them shine again?

    Show solution

    AnswerThe acid dissolves the basic copper carbonate (or oxide) coat.

    The dull green or dark coating is basic copper carbonate (and copper oxide), formed by the reaction of copper in the brass with moist air. These compounds are basic.

    Lemon juice contains citric acid and tamarind contains tartaric acid. The acid reacts with the basic coating, turning it into salts that wash away with water, and the fresh shiny metal beneath is exposed.

  14. Long answerMediumNCERT Exercises Q14

    Compare a metal and a non-metal on three chemical points: the oxide formed, the ion formed, and the reaction with dilute acids. Use sodium and sulphur as examples, and name one hydride formed by a non-metal.

    Show solution

    AnswerBasic vs acidic oxide; positive vs negative ion; displaces hydrogen vs does not.

    Table 3.12
    PointSodium (metal)Sulphur (non-metal)
    OxideNaX2O, basic; gives NaOHSOX2, acidic; gives HX2SOX3
    Ionloses 1 electron: NaX+gains 2 electrons: SX2−
    Dilute acidsdisplaces hydrogen (violently)no hydrogen

    Non-metals combine with hydrogen to form hydrides, for example hydrogen sulphide, HX2S.

  15. Short answerHardNCERT Exercises Q15

    A roadside polisher offers to make a dull pair of gold earrings shine 'like new'. He dips them for a minute in a fuming yellowish liquid, rinses them and hands them back gleaming. At home the earrings weigh 9.2 g instead of 10.0 g.

    1. Which liquid did he probably use?

      Show solution

      AnswerAqua regia

      Aqua regia, made fresh from three parts of concentrated HCl to one part of concentrated HNOX3, is one of the very few liquids that dissolve gold.

    2. What percentage of the mass of the earrings was lost?

      %
      Show solution

      Loss =10.0−9.2=0.8 g, so the percentage lost is 0.8/10.0×100=8 %. That gold stayed behind in his liquid.

    3. Why does neither of the two acids in the liquid do this on its own?

      Show solution

      AnswerOnly the mixture dissolves gold.

      Gold is so unreactive that neither concentrated acid alone attacks it; only the mixture, aqua regia, can dissolve it. The fresh gold surface underneath then shines.

  16. Short answerMediumNCERT Exercises Q16

    Solar water heaters and geysers often use copper tanks, or tanks lined with copper, rather than plain steel. Give two reasons.

    Show solution

    AnswerCopper does not react with hot water; it conducts heat well.

    Copper is below hydrogen in the reactivity series and does not react with water, even hot water. Steel, which is mostly iron, would rust in hot water containing dissolved air.

    Copper is also an excellent conductor of heat, so the water warms up quickly.

  17. Quick answerMedium

    Assertion (A): Aluminium vessels do not corrode easily, although aluminium is a reactive metal. Reason (R): A thin layer of aluminium oxide on the surface protects the metal beneath.

    Show answer

    Answer (A) Both A and R are true, and R explains A

    Both statements are true, and the protective oxide layer is exactly why aluminium resists corrosion.
  18. Quick answerMedium

    Assertion (A): Copper does not give hydrogen with dilute hydrochloric acid. Reason (R): Copper is above hydrogen in the reactivity series.

    Show answer

    Answer (C) A is true, but R is false

    A is true, but copper is below hydrogen, so R is false. Being below hydrogen is why copper gives no hydrogen.
  19. Quick answerEasy

    Heating a carbonate ore in little or no air is called , and heating a sulphide ore in plenty of air is called .

    Show answer

    Answer (1) calcination, (2) roasting

    Calcination is for carbonates in limited air; roasting is for sulphides in excess air.
  20. Quick answerMedium

    An aluminium atom has atomic number 13. How many electrons does it lose when it forms an ion?

    electrons
    Show answer

    Answer 3 electrons

    Aluminium is 2, 8, 3. Losing the three outer electrons leaves 2, 8, a full octet, so it forms AlX3+.

Find your NCERT exercise question

Our practice questions are written for ncert.ai and follow the NCERT exercises. Find the one that matches the question in your textbook; its answer is with it.

In your NCERT textbookPractice question here
NCERT in-text Questions p. 40, Q1Practice: physical properties (NCERT in-text questions, p. 40) · Q1
NCERT in-text Questions p. 40, Q2Practice: physical properties (NCERT in-text questions, p. 40) · Q2
NCERT in-text Questions p. 46, Q1Practice: reactivity (NCERT in-text questions, p. 46) · Q1
NCERT in-text Questions p. 46, Q2Practice: reactivity (NCERT in-text questions, p. 46) · Q2
NCERT in-text Questions p. 46, Q3Practice: reactivity (NCERT in-text questions, p. 46) · Q3
NCERT in-text Questions p. 46, Q4Practice: reactivity (NCERT in-text questions, p. 46) · Q4
NCERT in-text Questions p. 46, Q5Practice: reactivity (NCERT in-text questions, p. 46) · Q5
NCERT in-text Questions p. 49, Q1Practice: ionic compounds (NCERT in-text questions, p. 49) · Q1
NCERT in-text Questions p. 49, Q2Practice: ionic compounds (NCERT in-text questions, p. 49) · Q2
NCERT in-text Questions p. 53, Q1Practice: occurrence and extraction (NCERT in-text questions, p. 53) · Q1
NCERT in-text Questions p. 53, Q2Practice: occurrence and extraction (NCERT in-text questions, p. 53) · Q2
NCERT in-text Questions p. 53, Q3Practice: occurrence and extraction (NCERT in-text questions, p. 53) · Q3
NCERT in-text Questions p. 55, Q1Practice: corrosion and alloys (NCERT in-text questions, p. 55) · Q1
NCERT in-text Questions p. 55, Q2Practice: corrosion and alloys (NCERT in-text questions, p. 55) · Q2
NCERT in-text Questions p. 55, Q3Practice: corrosion and alloys (NCERT in-text questions, p. 55) · Q3
NCERT Exercises Q1Exercises · Q1
NCERT Exercises Q2Exercises · Q2
NCERT Exercises Q3Exercises · Q3
NCERT Exercises Q4Exercises · Q4
NCERT Exercises Q5Exercises · Q5
NCERT Exercises Q6Exercises · Q6
NCERT Exercises Q7Exercises · Q7
NCERT Exercises Q8Exercises · Q8
NCERT Exercises Q9Exercises · Q9
NCERT Exercises Q10Exercises · Q10
NCERT Exercises Q11Exercises · Q11
NCERT Exercises Q12Exercises · Q12
NCERT Exercises Q13Exercises · Q13
NCERT Exercises Q14Exercises · Q14
NCERT Exercises Q15Exercises · Q15
NCERT Exercises Q16Exercises · Q16

Quick check: MCQs on Metals and Non-metals

  1. 3.1.2 Non-metals4 questions
  2. 3.2.2 What happens when Metals react with Water?4 questions
  3. 3.2.5 The Reactivity Series4 questions
  4. 3.3.1 Properties of Ionic Compounds4 questions
  5. 3.4.6 Refining of Metals4 questions
  6. 3.5.1 Prevention of Corrosion4 questions
Glossary · 15

Key terms (English–Hindi)

alloyमिश्रातुmishraatu
A metal blended evenly with other metals or with a non-metal, such as brass or steel.First seen in the chapter →
amphoteric oxideउभयधर्मी ऑक्साइडubhaydharmi oxide
A metal oxide, such as AlX2OX3 or ZnO, that reacts with both acids and bases to give a salt and water.First seen in the chapter →
calcinationनिस्तापनnistaapan
Heating a carbonate ore strongly in little or no air to turn it into the oxide.First seen in the chapter →
corrosionसंक्षारणsankshaaran
The slow eating away of a metal by air, moisture or chemicals around it; rusting of iron is an example.First seen in the chapter →
ductileतन्यtanya
Able to be stretched into fine wire; gold can be drawn finer than any other metal.First seen in the chapter →
electrolytic refiningविद्युत-अपघटनी परिष्करणvidyut-apghatani parishkaran
Purifying a metal by electrolysis, with impure metal as the anode and pure metal as the cathode.First seen in the chapter →
galvanisationयशदलेपनyashadlepan
Giving iron or steel a thin coat of zinc to stop it rusting.First seen in the chapter →
gangueगैंगgaing
The soil, sand and rock mixed with an ore, removed before the metal is extracted.First seen in the chapter →
ionic compoundआयनिक यौगिकaayanik yaugik
A compound of positive and negative ions held by electrostatic attraction, formed by electron transfer from a metal to a non-metal.First seen in the chapter →
malleableआघातवर्ध्यaaghaatvardhya
Able to be beaten or rolled into thin sheets without breaking, as gold, silver and aluminium are.First seen in the chapter →
metallurgyधातुकर्मdhaatukarm
Getting metals out of their ores and purifying them for use.First seen in the chapter →
mineralखनिजkhanij
A naturally formed element or compound found in the Earth's crust.First seen in the chapter →
oreअयस्कayask
A mineral from which a metal can be extracted profitably.First seen in the chapter →
reactivity seriesसक्रियता श्रेणीsakriyata shreni
A list of metals from the most reactive (potassium) to the least reactive (gold), with hydrogen placed in it for comparison.First seen in the chapter →
roastingभर्जनbharjan
Heating a sulphide ore strongly in plenty of air to turn it into the oxide.First seen in the chapter →