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ExplorationCh 9 Atomic Foundations of Matter

Atomic Foundations of Matter: Class 9 Science · Chapter 9

Exploration · Companion notes, simulations and practice · Official NCERT chapter PDF ↗

Published · Updated

  • 95 min
  • 1 simulation
  • 37 practice questions
  • 30 MCQs

What you will learn in Atomic Foundations of Matter

  • Show by weighing that mass stays the same in physical and chemical changes, and explain why a gas must be trapped for this to show
  • Use the law of conservation of mass and the law of constant proportions to find unknown masses in reactions and compounds
  • State Dalton's postulates and use them to explain the two laws of chemical combination
  • Explain how atoms reach a stable octet or duplet by sharing electrons (covalent bonds) or transferring them (ionic bonds), and describe dot-and-cross diagrams of simple molecules and ions
  • Name simple covalent and ionic compounds and write their formulae from valencies, simplifying and using brackets for polyatomic ions
  • Compare ionic and covalent compounds by solubility, electrical conductivity and melting point, and explain the differences in terms of ions and molecules
  • Calculate molecular masses and formula unit masses from atomic masses

Original companion text aligned to NCERT Science Class 9, Chapter 9, pp. 162–183. Not affiliated with or endorsed by NCERT.

Does mass change when matter changes?

Chapter 8, Journey Inside the Atom, took you inside the atom: a nucleus of protons and neutrons, with electrons arranged in shells around it. It also showed that an atom is at its most stable when its outermost shell holds eight electrons, or two if that shell is the first (K) shell. This chapter picks up from there. It asks how atoms hold on to one another, how we write and name what they build, and how much the products of a reaction weigh.

Begin with a surprise from the kitchen shelf. Sodium is a soft, silvery metal that reacts violently with water, and chlorine is a choking, greenish-yellow gas. Joined together, they become sodium chloride: the harmless table salt in every namak-daani. A compound is a brand-new substance with properties of its own, not a mixture of its elements' properties. So here is a fair question: when one substance turns into another, does the total amount of matter change? A balance can answer that.

A physical change keeps every particle on the pan, so the reading holds steady. A chemical change makes new substances, and some of them may be gases. Does the balance still agree when that happens?

4/4The gas stays inside the bottle: still 158.9 g.

Fig. 9.1Gas that escapes is not weighed; gas that is trapped is.NCERT Fig. 9.2 · p. 164

A plastic bottle of vinegar stands on a digital kitchen scale. In the first step the bottle is open and a small bowl of baking soda sits beside it; the display reads 152.6 g. In the second step the soda has been tipped in, bubbles fill the liquid, arrows show gas leaving the open neck and the display has dropped to 152.1 g, marked lighter. In the third step a fresh bottle has its cap screwed on, with a tissue packet of soda hanging inside the neck; the display reads 158.9 g. In the fourth step the packet has fallen into the vinegar, bubbles rise, a label says the gas stays inside, and the display still reads 158.9 g, marked same.

Quick check
1 of 2
Which change would make the reading on a balance go down if it happened in an open container?
Show answer

Answer (D) Baking soda fizzing in vinegar

The fizz is a gas, carbon dioxide, which leaves an open container. Melting, dissolving and crushing are physical changes in which nothing leaves the pan.

9.1 Law of Conservation of Mass

The capped bottle shows something that holds for every chemical reaction ever measured. The vinegar and soda turned into new substances, including a gas, yet the total mass on the pan stayed fixed. The open bottle only seemed to lose mass because one product walked out of the experiment. The French chemist Antoine Lavoisier reached this conclusion in 1789 after years of weighing reactions in sealed glass vessels.

LawLaw of conservation of mass

In a chemical reaction, matter is neither created nor destroyed: the total mass of the products equals the total mass of the reactants.

This is the law of conservation of mass (द्रव्यमान संरक्षण का नियम). It gives chemists a powerful bookkeeping rule. If you know the masses of all but one substance in a reaction, the law tells you the missing one.

You can watch the same idea at the level of particles. The simulation below shows a warm container of water. With the lid off, fast-moving particles escape as vapour, and the mass left in the container falls. With the lid on, every particle stays inside, just as the gas stayed inside the capped bottle.

SimulationOpen or closed: where do the particles go?

A container of warm water drawn as moving particles, with a thermometer, a temperature slider and a lid switch. With the lid off, fast particles leave the surface and a counter shows how many have escaped and how many are left. With the lid on, particles that leave the liquid bounce back from the lid, so the escaped count stops rising and every particle stays in the container.

Fig. 9.2Press Play. The counter shows how many particles have escaped from the container.
Try this
  • Leave the lid off and press Play. How many particles escape in about 20 seconds?
  • Switch the lid on. Does the escaped counter still rise? Which set-up in Activity 9.2 is this like?
  • Raise the temperature with the lid off. Why would an open pan of boiling dal weigh less every minute?

We can write the reaction of Activity 9.3 as a word equation and as a balanced chemical equation. Count the atoms on each side of the chemical equation: every atom on the left turns up on the right.

word equation
sodium sulfate+barium chloride→barium sulfate+sodium chloride
(9.1)
NaX2SOX4+BaClX2→BaSOX4+2 NaCl
(9.2)
Example 9.1NCERT Example 9.1 · p. 166

Checking the law with measured masses

In a school laboratory, 1.20 g of magnesium ribbon is dropped into dilute hydrochloric acid containing 3.65 g of hydrogen chloride, inside a flask closed with a stopper. When the reaction is over, the flask contains 4.75 g of magnesium chloride and 0.10 g of hydrogen gas. Do these results obey the law of conservation of mass?

Try it yourself first. Then reveal the solution one step at a time.

Example 9.2NCERT Example 9.2 · p. 166

Scaling up from a known reaction

When magnesium burns in air, 24 g of magnesium combines with 16 g of oxygen to form 40 g of magnesium oxide. A student burns 6.0 g of magnesium completely. How much magnesium oxide forms, and how much oxygen is used?

Try it yourself first. Then reveal the solution one step at a time.

Quick check
1 of 3
A candle stands on a balance and burns for ten minutes. Why does the reading fall?
Show answer

Answer (D) Gases made by the burning escape into the room

Burning wax makes carbon dioxide and water vapour, which drift away. If they were trapped and weighed, the total mass would be at least as large as the wax burnt, since oxygen from the air joins in.

9.2 Law of Constant Proportions

The reactions so far all used compounds such as baking soda, magnesium oxide and sodium chloride. Here is a sharper question about them. Can hydrogen and oxygen join in any amounts to make water, a little more oxygen in one sample and a little less in another? Or is the recipe fixed?

In the 1790s the French chemist Joseph Proust answered this by analysing compounds collected from very different places and also made in the laboratory. Every pure sample of a compound had exactly the same make-up by mass. Try it with carbon dioxide. Collect some from three very different places: the air you breathe out, a glowing charcoal angithi and the fizz of a soda bottle. Purify each sample and analyse 11 g of it. Every one gives 3 g of carbon and 8 g of oxygen. Pure water is just as strict: one part hydrogen to eight parts oxygen by mass, every time.

3/3Carbon : oxygen is 3 : 8 by mass in every sample.

Fig. 9.3Pure carbon dioxide has the same composition by mass, whatever its source.NCERT Law of Constant Proportions · p. 167

Three rows are labelled breath, charcoal and soda. In the first step each row shows a grey bar labelled 11 g carbon dioxide. In the second step each bar splits into a shorter blue piece labelled 3 g carbon and a longer orange piece labelled 8 g oxygen. In the third step a line underneath reads always 3 : 8.

LawLaw of constant proportions

Every sample of a pure compound has the same make-up by mass: its elements are always in the same ratio, wherever the sample came from.

This is the law of constant proportions (स्थिर अनुपात का नियम). You will also see it called the law of definite proportions or Proust's law. It applies to compounds, not to mixtures: you can stir any amount of sugar into tea, but you cannot make water with a little extra oxygen.

Example 9.3NCERT Example 9.3 · p. 167

Using a fixed ratio, with a leftover

Iron sulfide (FeS) always contains iron and sulfur in the mass ratio 7 : 4. A student heats 14 g of iron filings with 10 g of sulfur powder until no more reaction takes place. How much sulfur reacts, how much is left over, and how much iron sulfide forms?

Try it yourself first. Then reveal the solution one step at a time.

Quick check
1 of 3
In pure carbon dioxide, the masses of carbon and oxygen are always in the ratio 3 : 8. How much oxygen is present in a sample that contains 6 g of carbon?
Show answer

Answer (C) 16 g

Double the carbon means double the oxygen: 6=2×3, so oxygen =2×8=16 g. 22 g is the mass of the whole sample, not of the oxygen.
Practice · 6 questions

Pause and ponder: questions with answers

  1. Short answerEasyPause and Ponder Q1

    During aarti, a small piece of camphor burns away completely in a diya and leaves nothing behind. Does this show that mass can be destroyed? Explain.

    Show solution

    AnswerNo. The camphor reacts with oxygen to form carbon dioxide and water vapour, which escape into the air.

    Burning is a chemical reaction between camphor and oxygen from the air. Its products, carbon dioxide and water vapour, are gases that mix into the room, so the diya looks empty. If all the gases could be collected and weighed, their mass would equal the mass of camphor plus the mass of oxygen used. Mass is conserved; it has only moved out of sight.

  2. NumericalEasyPause and Ponder Q2

    A 4.8 g piece of magnesium ribbon burns completely, using up 3.2 g of oxygen from the air. What mass of white magnesium oxide forms?

    g
    Show answer

    Answer 8 g

    By conservation of mass, 4.8+3.2=8.0 g of magnesium oxide. Check: 4.8:3.2=3:2, the same as 24:16, so neither reactant is left over.
  3. NumericalMediumPause and Ponder Q3

    Pure calcium carbonate, the substance of chalk and marble, is 40 % calcium by mass. How much calcium is there in a 25 g piece of pure calcium carbonate?

    g
    Show answer

    Answer 10 g

    40100×25=10 g of calcium. Every pure sample has the same 40 %, whatever its size or source.
  4. NumericalMediumPause and Ponder Q4

    In ammonia, nitrogen and hydrogen are combined in the mass ratio 14 : 3. What mass of hydrogen combines with 28 g of nitrogen, and what mass of ammonia forms?

    Show solution

    Answer6 g of hydrogen; 34 g of ammonia.

    28÷14=2, so the hydrogen needed is 2×3=6 g. By conservation of mass, ammonia formed =28+6=34 g.

  5. Short answerMediumPause and Ponder Q5

    Why does the law of constant proportions hold for compounds such as water but not for mixtures such as nimbu paani?

    Show solution

    AnswerA compound has a fixed recipe set by how its atoms join; a mixture's parts can be in any amounts.

    In a compound, atoms of the elements are joined in a fixed number ratio, and each kind of atom has a fixed mass, so the mass ratio is fixed too. In nimbu paani the water, lemon juice, sugar and salt are simply mixed, not joined chemically. You can add more sugar or less lemon, so the proportions change from glass to glass.

  6. Short answerMediumPause and Ponder Q6

    Two samples of magnesium oxide are analysed. Sample 1, bought from a chemical supplier, contains 3.0 g of magnesium combined with 2.0 g of oxygen. Sample 2, made by burning ribbon in the school laboratory, contains 7.2 g of magnesium combined with 4.8 g of oxygen. Do the results support the law of constant proportions?

    Show answer

    Answer (A) Yes: both ratios simplify to 3 : 2

    3.0:2.0=3:2 and 7.2:4.8=3:2. The amounts differ, but the proportion is the same, which is exactly what the law predicts.

9.3 Dalton’s Atomic Theory

The two laws describe what happens; they do not say why. Why should the products always weigh exactly as much as the reactants? Why should water never be 1 : 7 or 1 : 9? In 1808 the English teacher and scientist John Dalton offered an answer built on one bold idea: matter is made of tiny, indestructible particles called atoms.

Dalton stated his theory as a set of postulates (अभिधारणा). A postulate is a basic idea that a theory takes as its starting point. It is not proved directly; instead, scientists test the predictions that follow from it, and the postulate survives as long as those predictions keep matching experiments. Here are his postulates, sorted into two groups.

  • About atoms
    • Atoms are the tiny particles from which all matter is built, and they are what actually take part in a reaction.
    • No chemical reaction can split, create or destroy an atom.
    • Within one element every atom is alike in mass and behaviour, while different elements have atoms of different masses and behaviour.
  • About compounds
    • To form a compound, atoms join in small whole-number ratios, such as 1 : 1, 1 : 2 or 2 : 3.
    • Any particular compound always contains the same kinds of atoms, in the same relative numbers.

Now the two laws follow naturally. In a reaction, atoms only part company and join new partners, as Fig. 9.4 shows. No atom appears or vanishes, and each keeps its own mass, so the total mass cannot change. That is the law of conservation of mass. Then think of water. Every water molecule holds two hydrogen atoms (1 u each) and one oxygen atom (16 u). So every sample has 2 u of hydrogen for every 16 u of oxygen, which is 1 : 8. Fixed numbers of atoms with fixed masses give fixed mass ratios: the law of constant proportions.

4/4Four H and two O atoms before, four H and two O atoms after: the mass cannot change.

Fig. 9.4A reaction regroups atoms; it never makes or destroys them.

Atoms are drawn as balls: small blue balls marked H and larger orange balls marked O. In the first step, on the left, there are two hydrogen molecules, each a pair of H balls, and one oxygen molecule, a pair of O balls. In the second step each pair pulls slightly apart as the bonds break. In the third step the atoms move to the right and regroup as two water molecules, each an O ball with two H balls. In the fourth step labels underneath read before: 4 H, 2 O and after: 4 H, 2 O.

Quick check
1 of 3
Assertion (A): Every sample of pure carbon dioxide contains 3 g of carbon for every 8 g of oxygen. Reason (R): In carbon dioxide one carbon atom always joins two oxygen atoms, and each kind of atom has a fixed mass. Choose the correct option.
Show answer

Answer (A) A and R are both true, and R explains A

Both are true. One C atom (12 u) and two O atoms (32 u) give 12:32=3:8, so the fixed atom ratio and fixed atomic masses are exactly what produce the fixed mass ratio.

9.4 How Atoms Combine

Atoms seldom stay alone. Two oxygen atoms pair up to make an oxygen molecule, OX2, the form of oxygen in the air we breathe. This settles one of the opening questions: O stands for a single oxygen atom, while OX2 stands for a molecule of two. Atoms of different elements join too. One carbon atom and two oxygen atoms make a molecule of carbon dioxide, COX2, a compound.

Definition
Molecule

The smallest particle of a substance that can exist by itself: two or more atoms joined together, with no overall charge, showing the properties of that substance.

ExampleOX2 is a molecule of an element; COX2 is a molecule of a compound.

A few elements form no molecules at all. Helium, neon and argon already have full outer shells, so their atoms are stable on their own and the gases exist as separate atoms. That is why argon can fill an electric bulb without reacting with the hot filament.

Most other atoms have an outer shell that is not full: fewer than eight electrons, or fewer than two when the K shell is the only shell. Such an atom can reach a stable arrangement in one of two ways:

  • by sharing electrons with another atom, so that the shared electrons count for both atoms; or
  • by transferring electrons: one atom gives away one or more electrons and another atom takes them.

Either way, the joined atoms end up with less energy than they had apart. A system with lower energy is more stable, much as a marble resting at the bottom of a bowl is more settled than one balanced on its rim. Whatever keeps the atoms joined after this is called a chemical bond (रासायनिक आबंध).

Definition
Chemical bond

An attraction strong enough to keep two atoms (or ions) joined, so that they act as parts of one molecule or compound.

9.4.1 Bonding by sharing electrons: the covalent bond

Molecules of elements

Start with the smallest atom. Hydrogen (atomic number 1) has a single electron in its K shell, which has room for two. Two hydrogen atoms solve this together: each puts its electron into a shared pair that sits between the two nuclei. The pair counts for both atoms, so each now has two electrons around it, a full K shell. What holds the molecule together? The two positive nuclei are both pulled towards the negative pair between them, so neither atom can drift away.

Definition
Covalent bond

A chemical bond formed when two atoms share a pair of electrons, one electron usually coming from each atom.

ExampleThe bond in a hydrogen molecule, H–H.

A bond made of one shared pair is a single bond, drawn as one line: H–H. Chlorine (2, 8, 7) is one electron short of an octet, so two chlorine atoms also share one pair, Cl–Cl. Oxygen (2, 6) is two short. Two oxygen atoms therefore share two pairs, a double bond, drawn O=O. Nitrogen (2, 5) is three short, so the two atoms in NX2 share three pairs, a triple bond, N≡N. Step through Fig. 9.5 and count the electrons around each atom: in every molecule each atom ends up with a full shell.

4/5Oxygen atoms share two pairs: a double bond.

Fig. 9.5Shared pairs sit where the outer shells overlap. Dots and crosses only show where each electron came from; all electrons are identical.NCERT Figs 9.6–9.8 · p. 169

Each atom is drawn as a circle for its outer shell, with its symbol inside; electrons from one atom are dots and from the other atom are crosses. In the first step two hydrogen circles are apart, each with one electron. In the second step they overlap and the dot and cross sit together in the overlap, labelled H–H, one shared pair, single bond. In the third step two chlorine circles overlap with one shared pair and three unshared pairs on each atom, labelled Cl–Cl. In the fourth step two oxygen circles share two pairs, with two unshared pairs on each atom, labelled O=O, double bond. In the fifth step two nitrogen circles share three pairs, with one unshared pair on each atom, labelled N≡N, triple bond.

Molecules of compounds

Atoms of different elements share electrons in just the same way. Hydrogen needs one more electron and so does chlorine, so in hydrogen chloride they share one pair: H–Cl, a single bond. Oxygen needs two electrons, but a hydrogen atom can offer only one. So the oxygen atom shares one pair with each of two hydrogen atoms, making water, HX2O, with two single bonds. A compound whose atoms are held together by shared electrons is called a covalent compound.

Notice the pattern in Fig. 9.6: each hydrogen atom makes up for one missing electron. Nitrogen is three short, so it bonds to three hydrogen atoms in ammonia, NHX3. Carbon is four short, so it bonds to four in methane, CHX4, the main gas in the biogas from a gobar gas plant.

2/4Oxygen is two short: two hydrogens, two unshared pairs.

Fig. 9.6The number of hydrogen atoms equals the number of electrons the central atom is short of an octet.NCERT Figs 9.9–9.10 · p. 171

A large green circle for the outer shell of a central atom sits in the middle; small blue circles for hydrogen atoms overlap it. Dots are the central atom's electrons and crosses are hydrogen electrons. In the first step the central atom is Cl with one hydrogen on the right and three unshared pairs; a side note says Cl needs 1, so 1 hydrogen. In the second step it is O with hydrogens on the right and below and two unshared pairs. In the third step it is N with three hydrogens and one unshared pair. In the fourth step it is C with four hydrogens on all sides and no unshared pairs.

Naming covalent compounds

Many covalent compounds are made of just two non-metals. Their names tell you how many atoms of each element a molecule contains, using number prefixes taken from Greek.

Table 9.4Number prefixes
Number of atomsPrefix
1mono-
2di-
3tri-
4tetra-
5penta-
6hexa-
  1. Give each element a prefix for its number of atoms.
  2. Exception: the first element never takes mono-. One carbon and one oxygen make carbon monoxide, not monocarbon monoxide.
  3. Change the ending of the second element to -ide: oxygen to oxide, chlorine to chloride, sulfur to sulfide.
  4. When a prefix ending in a or o runs into a vowel, its last letter drops out, so mono- + oxide is written monoxide. A prefix ending in i keeps it, as in trioxide.
  5. A compound whose formula starts with hydrogen gets no prefix for the hydrogen at all.
  • NO: nitrogen monoxide
  • SOX2: sulfur dioxide, and SOX3: sulfur trioxide
  • CClX4: carbon tetrachloride
  • PClX5: phosphorus pentachloride
  • NX2O: dinitrogen monoxide, the 'laughing gas' once common in dentists' clinics
  • HCl: hydrogen chloride, and HX2S: hydrogen sulfide (hydrogen first, so no prefix)

A handful of compounds go by everyday names that you should always use: water, HX2O; ammonia, NHX3; and methane, CHX4.

Quick check
1 of 3
How many electrons are shared between the two atoms of an oxygen molecule?
Show answer

Answer (B) 4

A double bond is two shared pairs, which is four electrons. Eight is the number each oxygen atom ends up with around it, counting the shared ones.
Practice · 4 questions

Pause and ponder: questions with answers

  1. DiagramMediumPause and Ponder Q8

    Bromine (atomic number 35) has seven electrons in its outermost shell and exists as BrX2 molecules. Describe the dot-and-cross diagram of BrX2 and name the type of bond.

    Show solution

    AnswerOne shared pair (a single covalent bond, Br–Br) and three unshared pairs on each atom.

    Each bromine atom has 7 outer electrons and needs 1 more. Each atom puts one electron into a shared pair, so each now counts 8 outer electrons: 2 in the shared pair and 6 in three unshared pairs. Draw two overlapping circles with one dot and one cross in the overlap and three pairs of dots (or crosses) on the outer side of each atom. One shared pair is a single covalent bond, Br–Br.

  2. DiagramMediumPause and Ponder Q9

    Fluorine has atomic number 9. Explain how a hydrogen atom and a fluorine atom reach stable shells in a molecule of hydrogen fluoride, HF.

    Show solution

    AnswerThey share one pair: H gets a full K shell (2), F gets an octet (8). Single bond, H–F.

    Fluorine is 2, 7, so it is one electron short of an octet; hydrogen is one short of a full K shell. Each gives one electron to a shared pair. Hydrogen now has 2 electrons around it, and fluorine has 8 (the shared pair plus three unshared pairs). The single shared pair is a single covalent bond, H–F.

  3. DiagramHardPause and Ponder Q10

    Show how electrons are shared in each molecule.

    1. Carbon disulfide, CSX2 (carbon 2, 4; sulfur 2, 8, 6)

      Show solution

      AnswerS=C=S: two double bonds.

      Carbon needs 4 electrons and each sulfur needs 2. Carbon shares two pairs with each sulfur atom, giving two double bonds, S=C=S. Carbon then counts 8 electrons (four shared pairs) and each sulfur counts 8 (two shared pairs plus two unshared pairs). Carbon dioxide, O=C=O, is built the same way.

    2. Phosphine, PHX3 (phosphorus has atomic number 15)

      Show solution

      AnswerThree P–H single bonds and one unshared pair on P.

      Phosphorus is 2, 8, 5, so it is three short of an octet, like nitrogen. It shares one pair with each of three hydrogen atoms. Phosphorus ends with three shared pairs and one unshared pair, 8 electrons; each hydrogen has 2.

  4. Short answerEasyPause and Ponder Q11

    A bulb is filled with argon (atomic number 18). Why does argon neither share nor transfer electrons with the metal filament?

    Show solution

    AnswerArgon is 2, 8, 8: its outer shell is already full, so it has nothing to gain by bonding.

    Argon's electrons are arranged 2, 8, 8, so its outermost shell already holds a stable octet. Sharing, losing or gaining electrons would not make it more stable, so argon atoms stay single and unreactive. That is exactly why it is used to fill bulbs.

9.4.2 Bonding by electron transfer: the ionic bond

Sharing is not the only route to a full shell. An atom with only one, two or three electrons in its outer shell usually finds it easier to give them away than to collect five or more extra. An atom with five, six or seven outer electrons tends to gain the few it is missing, or to share. Lithium, sodium, magnesium and aluminium are typical givers among the first 18 elements. Which others can you find in Chapter 8's table of electron arrangements?

Take sodium (atomic number 11), arranged 2, 8, 1. If it loses its single outer electron, the full shell of eight beneath becomes its outer shell. But it now has 11 protons and only 10 electrons, so it carries one unit of positive charge. This charged particle is a sodium ion, written NaX+. An ion with a positive charge is a cation (धनायन).

sodium loses an electron
Na→NaX++eX−
(9.3)

Chlorine (2, 8, 7) does the opposite. It accepts one electron and completes its octet, giving 17 protons and 18 electrons: one unit of negative charge. This is a chloride ion, ClX−, and an ion with a negative charge is an anion (ऋणायन). Cations and anions together are called ions (आयन).

chlorine gains an electron
Cl+eX−→ClX−
(9.4)

3/4Now NaX+ (2, 8) and ClX− (2, 8, 8): both have octets.

Fig. 9.7Transfer, then attraction: sodium gives one electron, chlorine takes it, and the oppositely charged ions hold together.NCERT Figs 9.11–9.13 · p. 172

Two atoms are drawn with their electron shells as rings and electrons as dots: sodium on the left with 2, 8, 1 electrons and chlorine on the right with 2, 8, 7. Sodium's single outer electron is drawn as an open circle. In the second step a dashed arrow labelled 1 electron carries it across to the gap in chlorine's outer ring. In the third step sodium's empty outer ring has gone and both atoms sit in square brackets as ions: sodium ion, 2, 8, with a plus charge, and chloride ion, 2, 8, 8, with a minus charge. In the fourth step the ions move closer with a double-headed arrow labelled attract, and the words ionic bond appear below.

Opposite charges attract. Once sodium has handed its electron to chlorine, the NaX+ and ClX− ions pull on each other strongly, and sodium chloride is formed. This attraction is an ionic bond (आयनिक आबंध), and a compound held together this way is an ionic compound.

Definition
Ionic bond

The pull between ions of opposite charge, an electrostatic attraction, that holds them together in an ionic compound.

ExampleThe attraction between NaX+ and ClX− ions in common salt.

2/3Ions repeat in a checkerboard: every neighbour has the opposite charge.

Fig. 9.8One layer of the crystal. Each sodium ion touches four chloride ions in its layer, plus one above and one below: six in all.NCERT Fig. 9.14 · p. 173

Small blue circles marked plus are sodium ions and larger green circles marked minus are chloride ions. In the first step only one sodium ion and one chloride ion are shown side by side. In the second step a whole layer appears, seven ions across and five down, alternating plus and minus like a checkerboard. In the third step the other ions fade, and a dashed square links the central sodium ion to its four chloride neighbours in the layer.

Some atoms move two electrons. Magnesium (2, 8, 2) gives away two and becomes MgX2+. Oxygen (2, 6) and sulfur (2, 8, 6) each take two and become the oxide ion, OX2−, and the sulfide ion, SX2−. But a chlorine atom can accept only one electron. So when magnesium meets chlorine, two chlorine atoms are needed to take magnesium's two electrons, and the compound is MgClX2: one MgX2+ ion for every two ClX− ions (Fig. 9.9).

3/3One MgX2+ and two ClX−: the formula is MgClX2.

Fig. 9.9One magnesium atom needs two chlorine atoms to take its two outer electrons.

Only outer shells are drawn. A magnesium circle in the middle has two dots; a chlorine circle on each side has seven crosses. In the second step dashed arrows carry one magnesium electron to each chlorine atom. In the third step square brackets enclose all three ions, the magnesium shell is faded, and the electron arrangements change to 2, 8 for magnesium and 2, 8, 8 for each chlorine; charge labels show one magnesium ion with charge 2 plus and two chloride ions with charge minus, and the formula MgCl2 appears below.

Naming ionic compounds

The name of an ionic compound reads like a pair: first the cation, then the anion. Because metals tend to lose electrons and non-metals tend to gain them, the first word is usually a metal and the second a non-metal whose ending has changed to -ide. Some toothpastes contain sodium fluoride, sunscreens often contain zinc oxide, and old black-and-white films used silver bromide. A cation simply keeps the name of its element.

Some ions are groups of atoms bonded together that move about as one unit and carry one overall charge. These are polyatomic ions, such as sulfate, SOX4X2−, and ammonium, NHX4X+, the commonest positive one. Most polyatomic anions have names ending in -ate, not -ide; hydroxide, OHX−, is the familiar exception.

The size of the charge on an ion is its valency (संयोजकता), the combining capacity of the atom or group. Iron and copper can each form two different ions, so their names carry a label: ferrous (FeX2+) and ferric (FeX3+), cuprous (CuX+) and cupric (CuX2+). The two tables below, grouped by valency, list the ions used in this chapter.

Table 9.5Common cations, by valency
ValencyCations
1sodium NaX+, potassium KX+, lithium LiX+, silver AgX+, cuprous CuX+, ammonium NHX4X+
2magnesium MgX2+, calcium CaX2+, barium BaX2+, zinc ZnX2+, ferrous FeX2+, cupric CuX2+
3aluminium AlX3+, ferric FeX3+
Table 9.6Common anions, by valency (the polyatomic ones are ammonium among the cations and hydroxide, nitrate, hydrogencarbonate, carbonate, sulfate and phosphate here)
ValencyAnions
1fluoride FX−, chloride ClX−, bromide BrX−, iodide IX−, hydroxide OHX−, nitrate NOX3X−, hydrogencarbonate HCOX3X−
2oxide OX2−, sulfide SX2−, carbonate COX3X2−, sulfate SOX4X2−
3nitride NX3−, phosphate POX4X3−
Quick check
1 of 4
Aluminium is arranged 2, 8, 3. Which ion does an aluminium atom form?
Show answer

Answer (D) AlX3+, by losing three electrons

Losing three electrons leaves the full 2, 8 arrangement and 13 protons against 10 electrons: a charge of 3+. Gaining five would be far harder, and losing an electron makes an ion positive, never negative.
Practice · 4 questions

Pause and ponder: questions with answers

  1. Short answerEasyPause and Ponder Q12

    Fluorine has atomic number 9. Which ion does a fluorine atom form, and how?

    Show solution

    AnswerThe fluoride ion, FX−, by gaining one electron.

    Fluorine is 2, 7, one electron short of an octet. It gains one electron to become 2, 8. With 9 protons and 10 electrons it carries one negative charge: the fluoride ion, FX−.

  2. Quick answerMediumPause and Ponder Q13

    An aluminium atom gives away electrons to become AlX3+. An oxygen atom accepts electrons to become OX2−. So in aluminium oxide, aluminium ions combine with oxide ions.

    Show answer

    Answer (1) 3, (2) 2, (3) 2, (4) 3

    Two Al atoms give away 2×3=6 electrons and three O atoms accept 3×2=6, so the formula is AlX2OX3.
  3. DiagramMediumPause and Ponder Q14

    Use electron arrangements to show how each metal forms its cation and then its fluoride.

    1. Lithium (atomic number 3)

      Show solution

      AnswerLi (2, 1) → LiX+ (2); fluoride LiF.

      Lithium (2, 1) loses its one outer electron and becomes LiX+, arranged 2. A fluorine atom (2, 7) takes that electron and becomes FX− (2, 8). One LiX+ balances one FX−, so lithium fluoride is LiF.

    2. Magnesium (atomic number 12)

      Show solution

      AnswerMg (2, 8, 2) → MgX2+ (2, 8); fluoride MgFX2.

      Magnesium (2, 8, 2) loses two electrons and becomes MgX2+ (2, 8). Each fluorine atom can take only one, so two fluorine atoms are needed, giving two FX− ions. Magnesium fluoride is MgFX2.

  4. Short answerMediumPause and Ponder Q15

    Explain how potassium oxide, KX2O, forms from potassium atoms (2, 8, 8, 1) and an oxygen atom (2, 6).

    Show solution

    AnswerTwo K atoms each give one electron to one O atom: two KX+ ions and one OX2− ion.

    Each potassium atom loses its single outer electron and becomes KX+ (2, 8, 8). The oxygen atom needs two electrons to complete its octet, so it takes one from each of two potassium atoms and becomes OX2− (2, 8). The two KX+ ions and one OX2− ion attract each other, and the charges balance: 2×(+1)+(−2)=0.

9.5 Writing Chemical Formulae

A chemical formula (रासायनिक सूत्र) shows which elements a compound contains and in what proportion, using symbols and small numbers called subscripts. In HX2O, the subscript 2 belongs to hydrogen, and oxygen's unwritten subscript is 1. You could work out every formula by drawing electrons, as in Section 9.4, but valencies give a much quicker route.

9.5.1 Writing chemical formulae of covalent compounds

In a covalent compound, an element's valency is the number of electrons each of its atoms shares, which is also the number of bonds it forms. The common values are 1 for hydrogen and chlorine, 2 for oxygen and sulfur, 3 for nitrogen and 4 for carbon. Then follow four steps:

  1. Write the symbols of the elements side by side.
  2. Write each element's valency under its symbol.
  3. Cross the valencies over, so that each number becomes the subscript of the other symbol.
  4. Divide both subscripts by any common factor, and do not write a subscript of 1.
Table 9.7Formulae of covalent compounds from valencies
ElementsValenciesAfter crossingFormula
hydrogen, oxygen1, 2HX2OX1HX2O
nitrogen, hydrogen3, 1NX1HX3NHX3
carbon, oxygen4, 2CX2OX4COX2 (divide by 2)

Check each result against the bonds you counted in Fig. 9.5 and Fig. 9.6: water has two O–H bonds, ammonia three N–H bonds, and carbon dioxide two double bonds.

9.5.2 Writing chemical formulae of ionic compounds

For an ionic compound, the valency of each ion is the size of its charge, and the steps are almost the same:

  1. Write the symbol of the cation first, then the anion.
  2. Write each ion's charge number under its symbol.
  3. Cross the numbers over to become subscripts.
  4. Divide by any common factor, because the formula of an ionic compound shows the simplest whole-number ratio of its ions.
  5. If a polyatomic ion is needed more than once, put it in brackets with the subscript outside.
  6. Leave the charges out of the final formula.

4/4AlX2SX3: two ions of 3+ and three of 2− give +6−6=0.

Fig. 9.10Each ion's charge number becomes the other ion's subscript.NCERT 9.5.2 Examples · p. 176

The symbols Al and S are written large, with the names aluminium and sulfide above them. In the second step their charges, 3 plus and 2 minus, appear underneath. In the third step a coloured 3 slides from under Al up to the lower right of S, and a coloured 2 slides from under S to the lower right of Al, along dashed crossing arrows. In the fourth step the formula Al2S3 appears in a box, with a check below: 2 times plus 3 and 3 times minus 2 give a total of 0.

Whatever the ions, the test is the same: the positive charges must cancel the negative charges, because a compound as a whole is neutral. The table shows the method on six pairs of ions, including the two situations that need extra care, simplifying and brackets.

Table 9.8Formulae of ionic compounds by criss-crossing
IonsAfter crossingFormulaWhy
BaX2+, ClX−BaX1ClX2BaClX2a subscript 1 is not written
ZnX2+, OX2−ZnX2OX2ZnOdivide by 2
KX+, SOX4X2−KX2(SOX4)X1KX2SOX4one sulfate ion: no brackets
CaX2+, OHX−CaX1(OH)X2Ca(OH)X2two hydroxide ions: brackets
NHX4X+, COX3X2−(NHX4)X2(COX3)X1(NHX4)X2COX3two ammonium ions: brackets
AlX3+, POX4X3−AlX3(POX4)X3AlPOX4divide by 3

Two slips are common. Calcium hydroxide is Ca(OH)X2, not CaOHX2: without the brackets, the 2 would double only the hydrogen. And charges never appear in the finished formula. In barium chloride, for instance, you write just BaClX2. You can try any pair of ions yourself in the formula builder in Section 9.8.

Quick check
1 of 3
What is the formula of calcium nitrate?
Show answer

Answer (C) Ca(NOX3)X2

Calcium is 2+ and nitrate is 1−, so one CaX2+ needs two NOX3X− ions. Nitrate is polyatomic and appears twice, so it needs brackets: Ca(NOX3)X2. Without brackets the 2 would seem to belong to oxygen.
Practice · 3 questions

Pause and ponder: questions with answers

  1. Quick answerEasyPause and Ponder Q16

    Name each covalent compound.

    1. SiOX2:

      Show answer

      Answer silicon dioxide

      One silicon (no mono-), two oxygens: silicon dioxide, the main substance in sand.
    2. NX2OX3:

      Show answer

      Answer dinitrogen trioxide

      Two nitrogens (di-) and three oxygens (tri-): dinitrogen trioxide.
    3. PBrX3:

      Show answer

      Answer phosphorus tribromide

      One phosphorus, three bromines: phosphorus tribromide.
    4. SFX4:

      Show answer

      Answer sulfur tetrafluoride

      One sulfur, four fluorines: sulfur tetrafluoride.
  2. Short answerMediumPause and Ponder Q17

    Write the formula of each compound.

    1. calcium hydrogencarbonate

      Show solution

      AnswerCa(HCOX3)X2

      CaX2+ and HCOX3X− cross to 1 : 2. The polyatomic ion appears twice, so it goes in brackets: Ca(HCOX3)X2.

    2. nitrogen trichloride

      Show solution

      AnswerNClX3

      The name itself gives one nitrogen and three chlorines (valencies 3 and 1): NClX3.

    3. ferrous sulfide

      Show solution

      AnswerFeS

      Ferrous is FeX2+ and sulfide is SX2−. Crossing gives FeX2SX2, which simplifies to FeS.

    4. cupric nitrate

      Show solution

      AnswerCu(NOX3)X2

      Cupric is CuX2+ and nitrate is NOX3X−, so one copper ion needs two nitrate ions, in brackets: Cu(NOX3)X2.

  3. Short answerMediumPause and Ponder Q18

    Write the formula of the compound formed by each pair of ions.

    1. BaX2+ and OHX−

      Show solution

      AnswerBa(OH)X2

      Charges 2 and 1 cross to BaX1(OH)X2; two hydroxide ions need brackets: Ba(OH)X2, barium hydroxide.

    2. NHX4X+ and POX4X3−

      Show solution

      Answer(NHX4)X3POX4

      Charges 1 and 3 cross to three ammonium ions and one phosphate ion. Ammonium is polyatomic and appears three times, so it is bracketed: (NHX4)X3POX4, ammonium phosphate.

9.6 Properties of Ionic and Covalent Compounds

Ionic compounds are built from ions, and covalent compounds from molecules. Does that difference show up in how they behave? Activity 9.4 tests two everyday properties: whether a substance dissolves, and whether it lets an electric current through.

2/3Free ions drift to the oppositely charged rods: the bulb glows.

Fig. 9.11Only moving ions carry a current through the liquid.NCERT Fig. 9.15 · p. 178

A battery at the top left and a bulb at the top right are wired to two rods dipping into a beaker; the left rod is marked minus and the right rod plus. In the first step the beaker holds only dry salt crystals and the bulb is off. In the second step the beaker holds salt solution with plus ions and minus ions spread through it; the plus ions have shifted towards the minus rod and the minus ions towards the plus rod, and the bulb glows with rays around it. In the third step the beaker holds sugar solution with uncharged sugar molecules, labelled no charge, and the bulb is off.

Why the difference? An electric current is a flow of charge. In salt solution, the NaX+ and ClX− ions are free to drift, cations towards the negative rod and anions towards the positive rod, and that movement carries the current. In the dry crystal, each ion is gripped by its neighbours in the lattice and can only jiggle on the spot, so no charge flows and the bulb stays dark. Sugar dissolves as whole molecules with no charge, so even its solution cannot carry a current. Camphor and wax give no ions either.

What if an ionic compound is melted instead of dissolved? Melting also frees the ions from the lattice, so molten sodium chloride conducts electricity. A melted covalent substance, such as liquid wax, still has no ions and does not.

Water molecules are attracted to ions and can tug them out of a crystal one by one, which is why many ionic compounds dissolve in water. Covalent substances like wax and camphor are chemically more like kerosene and mix with it instead. Breaking up a lattice of strongly attracting ions takes a great deal of energy, so ionic compounds melt only at high temperatures: sodium chloride melts at 801 °C. The molecules of most covalent compounds attract each other far more weakly, so naphthalene melts at about 80 °C and candle wax at about 60 °C.

Compare

Ionic and covalent compounds at a glance

Ionic compounds

  • Made of cations and anions in a crystal lattice
  • Usually dissolve in water but not in kerosene
  • Conduct when dissolved or melted, but not as solids
  • High melting points (sodium chloride: 801 °C)

Covalent compounds

  • Made of separate molecules
  • Often dissolve in kerosene; a few, like sugar, dissolve in water
  • Usually do not conduct, even when dissolved or melted
  • Low melting points (naphthalene: about 80 °C)
Quick check
1 of 3
A white solid does not conduct electricity, either dry or when stirred into water, and it melts at 70 °C. It is most likely…
Show answer

Answer (B) a covalent compound

No ions in any state and a low melting point both point to a covalent compound. An ionic compound would conduct in water or when molten and would melt at a much higher temperature.
Practice · 2 questions

Pause and ponder: questions with answers

  1. Short answerMediumPause and Ponder Q19

    A student's notebook reads: 'Compound Z, white crystals. Dry crystals: bulb dark. Melted: bulb glows. Dissolved in water: bulb glows.' What kind of bonding does Z have? Explain.

    Show solution

    AnswerIonic bonding.

    Z conducts when melted or dissolved but not as a solid. That is the pattern of an ionic compound: its ions are locked in the crystal, but free to move, and so carry a current, once the crystal melts or dissolves. A covalent compound would not conduct in any of the three states.

  2. Short answerHardPause and Ponder Q20

    A dull white coat forms on aluminium cookware as the metal reacts with oxygen in the air. Aluminium has atomic number 13.

    1. Which ions do aluminium and oxygen form?

      Show solution

      AnswerAlX3+ and OX2−

      Aluminium is 2, 8, 3, so it loses three electrons to form AlX3+. Oxygen is 2, 6, so it gains two to form OX2−.

    2. What is the formula of the coat?

      Show solution

      AnswerAlX2OX3

      Crossing the charge numbers 3 and 2 gives AlX2OX3: 2×(+3)+3×(−2)=0.

    3. Would the oxide conduct electricity once melted?

      Show answer

      Answer (A) Yes, because its ions are free to move

      Aluminium oxide is ionic, and melting frees its ions. In fact, aluminium metal is extracted by passing electricity through aluminium oxide dissolved in a molten mineral.

9.7 Molecular Mass of Covalent Compounds

Atoms are far too light to weigh one at a time in grams, so chemists compare them on a scale of their own. The atomic mass unit, u, is one-twelfth of the mass of a carbon-12 atom, which is close to the mass of one proton or one neutron. On this scale a hydrogen atom has a mass of about 1 u and an oxygen atom 16 u. The table gives the rounded values used in school chemistry; chlorine's 35.5 u is an average, because natural chlorine is a mixture of two isotopes.

Table 9.10Rounded atomic masses
AtomMass (u)AtomMass (u)AtomMass (u)
H1Na23K39
C12Mg24Ca40
N14Al27Fe56
O16P31Cu63.5
F19S32Zn65
Li7Cl35.5Ba137

Finding a molecular mass is bookkeeping: count each kind of atom in the formula, multiply by its atomic mass, and total the results.

Definition
Molecular mass

The mass of one molecule in u, found by adding up the atomic masses of every atom it contains.

ExampleWater, HX2O: 2×1+16=18 u.

3/3One CaX2+ and two ClX−: formula unit mass of CaClX2 = 111 u.

Fig. 9.12Molecular mass and formula unit mass are both sums of atomic masses.NCERT 9.7–9.8 · p. 179

On the left, an ammonia molecule is drawn as one large N ball with three small H balls attached; tags read 14 u on nitrogen and 1 u on each hydrogen. In the second step the sum 14 + 1 + 1 + 1 = 17 u appears below. In the third step, on the right, a dashed box headed a formula unit holds one calcium ion and two chloride ions, tagged 40 u and 35.5 u each, with the sum 40 + 35.5 + 35.5 = 111 u below.

Example 9.4NCERT Example 9.4 · p. 179

Molecular mass of ammonia

Find the molecular mass of ammonia, NHX3. (N = 14 u, H = 1 u)

Try it yourself first. Then reveal the solution one step at a time.

Example 9.5NCERT Example 9.5 · p. 179

Molecular mass of glucose

Glucose, the sugar in ORS and in your blood, has the formula CX6HX12OX6. Find its molecular mass. (C = 12 u, H = 1 u, O = 16 u)

Try it yourself first. Then reveal the solution one step at a time.

Try the same sum for table salt and you hit a problem of words. A salt grain is one big lattice of ions (the salt crystal), with no separate NaCl molecules in it, so it has no molecular mass in the strict sense. Section 9.8 gives the word chemists use instead.

Quick check
1 of 3
Find the molecular mass of sulfuric acid, HX2SOX4. (H = 1 u, S = 32 u, O = 16 u)
u
Show answer

Answer 98 u

2×1+32+4×16=2+32+64=98 u.

9.8 Formula Unit Mass of Ionic Compounds

The formula of an ionic compound gives the simplest whole-number ratio of its ions. One group of ions in that ratio, such as one CaX2+ ion with two ClX− ions in calcium chloride, is called a formula unit. Add the atomic masses in one formula unit and you get the formula unit mass (सूत्र इकाई द्रव्यमान). The arithmetic is the same as for molecular mass. Only the name changes, as a reminder that a formula unit is a way of counting ions, not a particle that exists on its own. Gaining or losing an electron changes an atom's mass far too little to matter here.

Definition
Formula unit mass

The mass in u of one formula unit of an ionic compound (its simplest whole-number group of ions), found by adding up the atomic masses of every atom in it.

ExampleSodium chloride, NaCl: 23+35.5=58.5 u.

Example 9.6NCERT Example 9.6 · p. 179

Formula unit mass of calcium chloride

Calcium chloride, CaClX2, is sprinkled on roads in cold countries to melt ice. Find its formula unit mass. (Ca = 40 u, Cl = 35.5 u)

Try it yourself first. Then reveal the solution one step at a time.

Example 9.7NCERT Example 9.7 · p. 180

Formula unit mass with brackets

Calcium phosphate, CaX3(POX4)X2, is sold as a calcium supplement and is added to some food powders to stop them caking. Find its formula unit mass. (Ca = 40 u, P = 31 u, O = 16 u)

Try it yourself first. Then reveal the solution one step at a time.

InteractiveFormula builder

An interactive formula builder. Two menus pick a cation from fourteen (from sodium to ferric) and an anion from thirteen (from chloride to phosphate), each shown with its charge. A panel shows the two ions with their charges and a crossing sign. Numbered steps explain the criss-cross: the charge numbers swap, a common factor is divided out when there is one, brackets are added when a polyatomic ion appears more than once, and a check shows the positive and negative charges adding to zero. A result box shows the formula, the compound's name and the formula unit mass worked out from rounded atomic masses. A checkbox hides the answer until a Show button is pressed, so learners can predict first, and buttons pick a random pair or reset.

Fig. 9.13Pick a cation and an anion. The builder crosses the charges, simplifies, adds brackets and works out the formula unit mass.
Quick check
1 of 3
Find the formula unit mass of magnesium chloride, MgClX2. (Mg = 24 u, Cl = 35.5 u)
u
Show answer

Answer 95 u

24+2×35.5=24+71=95 u.
Recap

Atomic Foundations of Matter: key points and summary

  1. In a chemical reaction the products weigh exactly as much as the reactants; mass only seems to change when a gas escapes or is taken in (Section 9.1).
  2. A pure compound has a fixed recipe by mass, so samples from anywhere match: carbon dioxide is always 3 : 8 carbon to oxygen, and water 1 : 8 hydrogen to oxygen (Section 9.2).
  3. Dalton explained both laws: atoms are not made or destroyed in reactions, they only regroup, and they join in fixed whole-number ratios (Section 9.3).
  4. Atoms join into molecules such as OX2 and COX2, which can exist on their own; noble gases stay as single atoms (Section 9.4).
  5. Atoms bond to reach a full outer shell and lower their energy, by sharing electrons or by transferring them; the attraction that results is a chemical bond (Section 9.4).
  6. A covalent bond is a shared pair of electrons: one pair in H–H and Cl–Cl, two in O=O, three in N≡N (Section 9.4.1).
  7. Two-element covalent compounds are named with number prefixes: SOX3 is sulfur trioxide and NX2O is dinitrogen monoxide (Naming covalent compounds).
  8. An ionic bond is the attraction between a cation (an atom that lost electrons) and an anion (an atom that gained them); ionic solids are 3-D crystal lattices (Section 9.4.2).
  9. Ionic compounds are named cation first; polyatomic ions such as SOX4X2− and NHX4X+ act as single units (Naming ionic compounds).
  10. To write a formula, cross over the valencies or charges, simplify, and bracket a polyatomic ion that appears more than once; the charges must add up to zero (Section 9.5).
  11. Ionic compounds usually dissolve in water, conduct when dissolved or melted, and melt at high temperatures; covalent compounds usually do not conduct (Section 9.6).
  12. Molecular mass (for molecules) and formula unit mass (for ionic compounds) are sums of atomic masses: HX2SOX4 is 98 u and CaClX2 is 111 u (Section 9.7, Section 9.8).
Practice · 18 questions

Practice questions with answers (NCERT “Revise, reflect, refine”)

  1. Short answerMediumNCERT Exercises Q1

    A student's flash card reads: 'Element P: atomic number 12. Element Q: atomic number 9.'

    1. Write the electron arrangement of each, and say which ion each forms.

      Show solution

      AnswerP is 2, 8, 2 and forms PX2+; Q is 2, 7 and forms QX−.

      P (12 electrons) is 2, 8, 2. Losing its two outer electrons leaves a full shell, so it forms a cation with charge 2+. Q (9 electrons) is 2, 7; gaining one electron completes its octet, so it forms an anion with charge 1−.

    2. What type of bond forms when P and Q combine?

      Show answer

      Answer (A) Ionic

      P transfers electrons to Q, so oppositely charged ions form and attract: an ionic bond.
    3. Write the formula of the compound.

      Show solution

      AnswerPQX2

      Charges 2+ and 1− cross to PX1QX2, written PQX2. (P is magnesium and Q is fluorine, so the compound is MgFX2.)

  2. DiagramHardNCERT Exercises Q2

    A colourless gas that makes up most of the air is made of diatomic molecules. Its atoms have atomic number 7.

    1. Write the electron arrangement of the atom and explain why two atoms join.

      Show solution

      Answer2, 5: each atom is three short of an octet; sharing completes both.

      Seven electrons fill the shells as 2, 5. On its own, each atom is three electrons short of an octet. If two atoms share three pairs, both can count eight electrons, so they join as NX2.

    2. What kind of bond holds the molecule together?

      Show answer

      Answer (C) A triple covalent bond

      Three shared pairs make a triple bond, N≡N.
    3. The same element combines with hydrogen. Give the formula of the compound and describe its bonds.

      Show solution

      AnswerNHX3: three single N–H bonds and one unshared pair on N.

      Nitrogen needs three electrons and each hydrogen atom can share one, so three hydrogen atoms bond to one nitrogen atom, each through a single covalent bond. Nitrogen keeps one unshared pair, so it counts 8 electrons; each hydrogen counts 2. The compound is ammonia, NHX3.

  3. Quick answerMediumNCERT Exercises Q3

    A formula unit of an ionic compound contains three cations and two anions, and its charges balance. Which pair of ions could it be made of?

    Show answer

    Answer (D) CaX2+ and POX4X3−

    Three CaX2+ give +6 and two POX4X3− give −6: CaX3(POX4)X2. Aluminium oxide has two cations and three anions, sodium sulfate two and one, and magnesium chloride one and two.
  4. Quick answerMediumNCERT Exercises Q4

    Which of these statements are correct? Select all that apply.

    Select all that apply
    Show answer
    Answer
    • (A) A molecule of ozone, OX3, contains three oxygen atoms.
    • (C) A molecule of ammonia contains four atoms.
    A is true (three O atoms) and C is true (one N and three H). B is false: noble gases such as helium and argon exist as single atoms. D is false: carbon shares two pairs with each oxygen atom, so both bonds are double bonds, O=C=O.
  5. Short answerMediumNCERT Exercises Q5

    Write the chemical formula of each compound.

    1. zinc nitrate

      Show solution

      AnswerZn(NOX3)X2

      ZnX2+ and NOX3X−: one zinc needs two nitrates, in brackets: Zn(NOX3)X2.

    2. barium oxide

      Show solution

      AnswerBaO

      BaX2+ and OX2− cross to BaX2OX2, which simplifies to BaO.

    3. ferric sulfate

      Show solution

      AnswerFeX2(SOX4)X3

      Ferric is FeX3+ and sulfate is SOX4X2−. Crossing gives two iron ions and three sulfate ions: FeX2(SOX4)X3. Check: 2×3=6 and 3×2=6.

    4. cupric hydroxide

      Show solution

      AnswerCu(OH)X2

      Cupric is CuX2+ and hydroxide is OHX−, so two hydroxide ions in brackets: Cu(OH)X2.

  6. Short answerMediumNCERT Exercises Q6

    Write the formula of the compound formed by each pair of ions.

    1. BaX2+ and FX−

      Show solution

      AnswerBaFX2

      Charges 2 and 1 cross to BaX1FX2: BaFX2.

    2. NHX4X+ and SOX4X2−

      Show solution

      Answer(NHX4)X2SOX4

      Two ammonium ions balance one sulfate ion. Ammonium appears twice, so it is bracketed: (NHX4)X2SOX4.

    3. LiX+ and COX3X2−

      Show solution

      AnswerLiX2COX3

      Two lithium ions balance one carbonate ion. Carbonate appears once, so no brackets: LiX2COX3.

    4. FeX3+ and NOX3X−

      Show solution

      AnswerFe(NOX3)X3

      Three nitrate ions balance one ferric ion: Fe(NOX3)X3.

  7. Quick answerEasyNCERT Exercises Q7

    Magnesium has atomic number 12. Which electron arrangement belongs to the magnesium ion, MgX2+?

    Show answer

    Answer (B) 2, 8

    MgX2+ has 12−2=10 electrons, arranged 2, 8. The arrangement 2, 8, 2 is the neutral atom, and 2, 8, 4 would mean it had gained electrons.
  8. NumericalMediumNCERT Exercises Q8

    Find the molecular mass or formula unit mass of each substance. (H = 1, C = 12, N = 14, O = 16, S = 32, K = 39, Ca = 40, all in u)

    1. ammonium sulfate, (NHX4)X2SOX4, a fertiliser

      u
      Show answer

      Answer 132 u

      2×(14+4)+32+4×16=36+32+64=132 u.
    2. urea, CO(NHX2)X2, the most widely used nitrogen fertiliser (a covalent compound)

      u
      Show answer

      Answer 60 u

      Molecular mass =12+16+2×(14+2)=28+32=60 u.
    3. potassium nitrate, KNOX3, used in fertilisers and fireworks

      u
      Show answer

      Answer 101 u

      39+14+3×16=101 u.
    4. calcium carbonate, CaCOX3, the substance of chalk and marble

      u
      Show answer

      Answer 100 u

      40+12+3×16=100 u.
  9. Short answerMediumNCERT Exercises Q9

    Write the formula of the compound formed when each pair of elements reacts.

    1. potassium and oxygen

      Show solution

      AnswerKX2O

      KX+ and OX2− cross to KX2O.

    2. aluminium and sulfur

      Show solution

      AnswerAlX2SX3

      AlX3+ and SX2− cross to AlX2SX3.

    3. barium and nitrogen

      Show solution

      AnswerBaX3NX2

      Barium forms BaX2+ and nitrogen (2, 5) gains three electrons to form the nitride ion NX3−. Crossing gives BaX3NX2.

    4. lithium and fluorine

      Show solution

      AnswerLiF

      LiX+ and FX− combine 1 : 1: LiF.

  10. Short answerMediumNCERT Exercises Q10

    Copy and complete the grid with the formula of the compound made by each cation (left) and anion (top). One cell is done for you.

    Table 9.11
    OHX−OX2−POX4X3−
    KX+KOH??
    CaX2+???
    AlX3+???
    Show solution
    Table 9.12
    OHX−OX2−POX4X3−
    KX+KOHKX2OKX3POX4
    CaX2+Ca(OH)X2CaOCaX3(POX4)X2
    AlX3+Al(OH)X3AlX2OX3AlPOX4

    Equal charges cancel one-for-one (CaO, AlPOX4). Brackets appear only where a polyatomic ion occurs more than once, as in Ca(OH)X2 and CaX3(POX4)X2.

  11. NumericalMediumNCERT Exercises Q11

    Zinc granules react with dilute sulfuric acid. In a closed flask, 6.5 g of zinc and 9.8 g of sulfuric acid give 16.1 g of zinc sulfate and 0.2 g of hydrogen gas.

    1. Show that these masses obey the law of conservation of mass.

      Show solution

      AnswerReactants 16.3 g = products 16.3 g.

      Reactants: 6.5+9.8=16.3 g. Products: 16.1+0.2=16.3 g. The totals are equal, so the law holds.

    2. The same reaction is done in an open beaker on a balance, and all the hydrogen escapes. What mass does the balance show for the contents at the end?

      g
      Show answer

      Answer 16.1 g

      Only the gas leaves: 16.3−0.2=16.1 g. The law still holds; the balance simply no longer weighs the hydrogen.
  12. Short answerMediumNCERT Exercises Q12

    A particle has 16 protons, 16 neutrons and 18 electrons.

    1. What are its atomic number and mass number?

      Show solution

      AnswerAtomic number 16; mass number 32.

      Atomic number = number of protons = 16. Mass number = protons + neutrons = 16+16=32.

    2. Does it carry a charge? If so, is it a cation or an anion, and why?

      Show solution

      AnswerAn anion with charge 2−.

      It has two more electrons (18) than protons (16), so its charge is 16−18=−2: an anion.

    3. Write its electron arrangement.

      Show solution

      Answer2, 8, 8

      18 electrons fill the shells as 2, 8, 8.

    4. Name the particle.

      Show solution

      AnswerThe sulfide ion, SX2−.

      Atomic number 16 is sulfur, and a sulfur atom that has gained two electrons is the sulfide ion, SX2−.

  13. Short answerHardNCERT Exercises Q13

    Atoms of two non-metals, A and B, contain 6 and 8 electrons respectively.

    1. Write each electron arrangement and say how many electrons each atom needs to complete its octet.

      Show solution

      AnswerA is 2, 4 and needs 4; B is 2, 6 and needs 2.

      A (6 electrons) is 2, 4, so it needs 4 more. B (8 electrons) is 2, 6, so it needs 2 more.

    2. Will A and B form an ionic or a covalent compound? Explain.

      Show solution

      AnswerCovalent: they share electrons.

      Both are non-metals. A would have to lose or gain four electrons, which takes far too much energy, and B holds its own electrons too tightly to give any away. So neither atom hands electrons over; instead they share pairs, which makes covalent bonds.

    3. Write the formula of the compound and name it.

      Show solution

      AnswerABX2, which is COX2, carbon dioxide.

      Valencies 4 and 2 cross to AX2BX4, which simplifies to ABX2. A is carbon and B is oxygen, so the compound is carbon dioxide, COX2, with two double bonds, O=C=O.

  14. Quick answerMediumNCERT Exercises Q14

    Assertion (A): Naphthalene dissolves in kerosene but not in water. Reason (R): Naphthalene is an ionic compound.

    Show answer

    Answer (C) A is true, but R is false

    A is true. R is false: naphthalene is a covalent compound made of molecules, which is exactly why it dissolves in kerosene and not in water, does not conduct, and melts at only about 80 °C.
  15. Short answerMediumNCERT Exercises Q15

    Find the numbers of electrons and neutrons in each particle.

    1. X24X2224MgX2+ (atomic number 12)

      Show solution

      Answer10 electrons, 12 neutrons

      Electrons: 12−2=10. Neutrons: 24−12=12.

    2. X19X2219FX− (atomic number 9)

      Show solution

      Answer10 electrons, 10 neutrons

      Electrons: 9+1=10. Neutrons: 19−9=10.

    3. X56X2256FeX3+ (atomic number 26)

      Show solution

      Answer23 electrons, 30 neutrons

      Electrons: 26−3=23. Neutrons: 56−26=30.

  16. Quick answerEasy

    Put the steps for writing the formula of an ionic compound in order.

    1. Divide by a common factor
    2. Cross the numbers over
    3. Write the charges below
    4. Check the charges cancel
    5. Write cation, then anion
    Show answer
    Answer
    1. Write cation, then anion
    2. Write the charges below
    3. Cross the numbers over
    4. Divide by a common factor
    5. Check the charges cancel
    Symbols first, then charges, cross, simplify, and finally check that the total charge is zero.
  17. Quick answerEasy

    Match each substance with the particles it is made of.

    Tap an item on the left, then its match on the right.

    Show answer
    Answer
    • sodium chloride : ions in a lattice
    • argon : single atoms
    • oxygen gas : molecules of an element
    • water : molecules of a compound
    Salt is ionic, argon is a noble gas, oxygen exists as OX2 molecules and water as HX2O molecules.
  18. Quick answerMedium

    A particle has 13 protons and 10 electrons. Its charge is .

    Show answer

    Answer 3+

    13−10=3 more protons than electrons, so the charge is 3+. It is the aluminium ion, AlX3+.

Find your NCERT exercise question

Our practice questions are written for ncert.ai and follow the NCERT exercises. Find the one that matches the question in your textbook; its answer is with it.

In your NCERT textbookPractice question here
Pause and Ponder Q1Pause and ponder · Q1
Pause and Ponder Q2Pause and ponder · Q2
Pause and Ponder Q3Pause and ponder · Q3
Pause and Ponder Q4Pause and ponder · Q4
Pause and Ponder Q5Pause and ponder · Q5
Pause and Ponder Q6Pause and ponder · Q6
Pause and Ponder Q8Pause and ponder · Q8
Pause and Ponder Q9Pause and ponder · Q9
Pause and Ponder Q10Pause and ponder · Q10
Pause and Ponder Q11Pause and ponder · Q11
Pause and Ponder Q12Pause and ponder · Q12
Pause and Ponder Q13Pause and ponder · Q13
Pause and Ponder Q14Pause and ponder · Q14
Pause and Ponder Q15Pause and ponder · Q15
Pause and Ponder Q16Pause and ponder · Q16
Pause and Ponder Q17Pause and ponder · Q17
Pause and Ponder Q18Pause and ponder · Q18
Pause and Ponder Q19Pause and ponder · Q19
Pause and Ponder Q20Pause and ponder · Q20
NCERT Exercises Q1Revise, reflect, refine · Q1
NCERT Exercises Q2Revise, reflect, refine · Q2
NCERT Exercises Q3Revise, reflect, refine · Q3
NCERT Exercises Q4Revise, reflect, refine · Q4
NCERT Exercises Q5Revise, reflect, refine · Q5
NCERT Exercises Q6Revise, reflect, refine · Q6
NCERT Exercises Q7Revise, reflect, refine · Q7
NCERT Exercises Q8Revise, reflect, refine · Q8
NCERT Exercises Q9Revise, reflect, refine · Q9
NCERT Exercises Q10Revise, reflect, refine · Q10
NCERT Exercises Q11Revise, reflect, refine · Q11
NCERT Exercises Q12Revise, reflect, refine · Q12
NCERT Exercises Q13Revise, reflect, refine · Q13
NCERT Exercises Q14Revise, reflect, refine · Q14
NCERT Exercises Q15Revise, reflect, refine · Q15

Quick check: MCQs on Atomic Foundations of Matter

  1. Does mass change when matter changes?2 questions
  2. 9.1 Law of Conservation of Mass3 questions
  3. 9.2 Law of Constant Proportions3 questions
  4. 9.3 Dalton’s Atomic Theory3 questions
  5. Naming covalent compounds3 questions
  6. Naming ionic compounds4 questions
  7. 9.5.2 Writing chemical formulae of ionic compounds3 questions
  8. 9.6 Properties of Ionic and Covalent Compounds3 questions
  9. 9.7 Molecular Mass of Covalent Compounds3 questions
  10. 9.8 Formula Unit Mass of Ionic Compounds3 questions
Glossary · 15

Key terms (English–Hindi)

anionऋणायनrinayan
A negatively charged ion, formed when an atom gains electrons, such as ClX−.First seen in the chapter →
cationधनायनdhanayan
A positively charged ion, formed when an atom loses electrons, such as NaX+.First seen in the chapter →
chemical bondरासायनिक आबंधrasayanik aabandh
The force of attraction that holds atoms or ions together.First seen in the chapter →
chemical formulaरासायनिक सूत्रrasayanik sutra
Symbols and subscripts showing the elements in a substance and their proportions, such as HX2O.First seen in the chapter →
covalent bondसहसंयोजी आबंधsahsanyoji aabandh
A bond formed when two atoms share a pair of electrons.
formula unit massसूत्र इकाई द्रव्यमानsutra ikai dravyaman
The mass in u of one formula unit (the simplest ion ratio) of an ionic compound, found by adding atomic masses.First seen in the chapter →
ionआयनaayan
An atom or group of atoms that carries an electric charge because it has lost or gained electrons.First seen in the chapter →
ionic bondआयनिक आबंधaayanik aabandh
The electrostatic attraction between oppositely charged ions.First seen in the chapter →
law of conservation of massद्रव्यमान संरक्षण का नियमdravyaman sanrakshan ka niyam
In a chemical reaction the total mass of the products equals the total mass of the reactants; matter is neither created nor destroyed.First seen in the chapter →
law of constant proportionsस्थिर अनुपात का नियमsthir anupat ka niyam
Every pure sample of a compound has its elements in the same ratio by mass, wherever it comes from.First seen in the chapter →
molecular massआण्विक द्रव्यमानaanvik dravyaman
The mass of one molecule in u, found by adding up the atomic masses of every atom in it.
moleculeअणुanu
The smallest particle of a substance that can exist by itself: two or more joined atoms with no overall charge.
polyatomic ionबहुपरमाणुक आयनbahuparmanuk aayan
A charged group of bonded atoms that acts as one unit, such as SOX4X2− or NHX4X+.First seen in the chapter →
postulateअभिधारणाabhidharana
A basic idea taken as the starting point of a theory; it is tested through the predictions that follow from it.First seen in the chapter →
valencyसंयोजकताsanyojakta
The combining capacity of an atom or ion: the number of electrons it shares, or the size of its charge.First seen in the chapter →